FISHER SCIENTIFIC CHEMICAL -- AMMONIUM BICARBONATE, A643500 -- 6810-00N057855
===================== Product Identification ===================== Product ID:AMMONIUM BICARBONATE, A643500 MSDS Date:01/30/1987 FSC:6810 NIIN:00N057855 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL Address:1 REAGENT LN Box:07410 City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM BICARBONATE (1:1) (CERCLA) CAS:1066-33-7 RTECS #:BO8600000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT: CHEMICAL REMAINS (APPOX. 10-20 MIN.) GET MED ATTN. SKIN:REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFECT (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:AREA W/SOAP/MILD DETERGENT & LG AMTS OF H*20 UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN. RTECS #:9999999ZZ Ingred Name:SPILL PROC:STOP LEAK IF YOU CAN DO IT W/OUT RISK. FOR SMALL SPILLS, TAKE UP W/SAND/OTHER ABSORB MATL & PLACE (SEE ING 5) RTECS #:9999999ZZ Ingred Name:ING 5:SWEEP UP AND PLACE IN SUITABLE (FIREBOARD), CONTAINERS FOR LATER DISPOSAL. RTECS #:9999999ZZ Ingred Name:PH:7.8 IN 0.1 N SOLUTION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE RESP IRRIT & COUGHING. INGEST:INGEST OF VERY LARGE DOSES MAY CAUSE CONJUNCT. EYES:PARTICULATES IN EYE MAY CAUSE IRRIT, LACRIMATIONS, REDNESS, PAIN, BURNING & BLURRED VISION. SKIN :CONTACT MAY CAUSE IRRIT. CHRONIC:INHAL:MAY CAUSE MUCOUS MEMBRANE IRRIT. EYES:PROLONGED/REPEATED CONTACT MAY (SUPDAT) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:AMMONIUM BICARBONATE IS HIGHLY TOXIC BY INTRAVENOUS INJECTION. IT IS A COMMON FOOD AND PHARMACEUTICAL ADDITIVE AND IS CONSIDERED NON-TOXIC ORALLY. IT MAY BE IRRITATING TO THE EYES, SKIN, AND MUCOUS M EMBRANES IN POWDER FORM. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSE AREA TO FRESH AIR IMMED. IF BREATHING HAS STOPPED, GIVE ARTIFICAL RESP. KEEP AFFECTED PERSON WARM & @ REST. GET MED ATTN. INGEST:IF VICTIM IS CONSCIOUS, GIVE HIM LRG QTYIES OF H*2O IMMED TO DILUTE. DO NOT INDUCE VOMIT. GET MED ATTN IMMED. EYE:WASH EYES IMMED W/LRG AMTS OF H*20, FOR @ LEAST 15 MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVD SCBA & FULL PROTECTIVE EQUIPMENT . MOVE CNTR FROM FIRE AREA IF POSSIBLE. DO NOT SCATTER SPILLED MATERIAL W/MORE H*2O THAN (SUPDAT) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE AND NEGLIGIBLE EXPLOSION HAZARD IN DUST FORM WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SOIL SPILL:DIG HOLDING AREA SUCH AS PIT, POND/LAGOON TO CONTAIN SPILLED MATL. USE PROCT COVER SUCH AS PLASTIC SHEET TO PREVENT DISSOLVING IN FIRE-FIGHTING H*2O/RAIN. H*2O SPILL: NEUT W/DILUTE ACID/REM OVABLE STRONG ACID. OCCUPATIONAL SPILL:(SEE ING 4) Neutralizing Agent:WATER SPILL: NEUTRALIZE WITH DILUTE ACID OR REMOVABLE STRONG ACID. ====================== Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:HIGH LEVELS-CHEMICAL CARTRIDGE RESPIRATOR NIOSH/MSHA APPROVED FOR PROTECTION AGAINST AMMONIA, DUSTS, & MISTS. Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EYEWASH FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:NEED FOR FIRE CTL. DIKE FIRE CONTROL H*2O FOR LATER DISP. USE AGENT SUITABLE FOR SURROUND FIRE. AVOID BRTHING HAZ VAPORS/DUST, KEEP UPWIND. HLTH HAZ:CHRONIC:EYES:CAUSE CONJUNCT. SKIN:M AY CAUSE DERMATITIS. FIRST AID PROC:CHEMICAL REMAINS (APPROX. 10-20 MIN). GET MED ATTN IMMED. (SEE ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:118F,48C Spec Gravity:1.6 pH:ING.7 Solubility in Water:17.4% Appearance and Odor:SHINY, HARD, WHITE CRYSTALS WITH A FAINT ODOR OF AMMONIA. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DECOMPOSES ON CONTACT WITH WATER OR ON HEATING. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES & PRESS UP TO THE MELTING POINT, 48 C, WHERE DECOMP OCCURS. AVOID HEATING TO DECOMP. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE HIGH TOXIC FUMES OF AMMONIA, AND OXIDES OF CARBON. Conditions to Avoid Polymerization:AVOID HEATING TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.