FISHER SCIENTIFIC, CHEMICAL DIVISION -- TERT-BUTANOL -- 6810-00-460-2091
===================== Product Identification ===================== Product ID:TERT-BUTANOL MSDS Date:11/03/1988 FSC:6810 NIIN:00-460-2091 === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIVISION Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7523(CHEMTREC 800-429-9300) Preparer's Name:GASTON L. PILLORI CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:TERT-BUTYL ALCOHOL (SARA III) CAS:75-65-0 RTECS #:EO1925000 Fraction by Wt: >99% OSHA PEL:100 PPM ACGIH TLV:100PPM 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 3500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTES: INHALE- SHORTNESS OF BREATH, CNS DEPRESSION. SKIN-REDNESS, IRRITATION, ERYTHEMA, HYPEREMIA. EYE- IRRITATION, REDNESS, PAIN, BLURRED VISION. INGEST- ABDOMINAL PAIN, CNS DEPRESSION, LIVER DAMAGE . CHRONIC: EYE- CONJUNCTIVITIS. SKIN- DRYING AND CRACKING. INHALE- REVERSIBLE LIVER, KIDNEY, AND HEART. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:IRRITATION, COUGHING, SHORTNESS OF BREATH, DIZZINESS, DROWSINESS, VERTIGO, NAUSEA, VOMITING, FATIGUE, REDNESS OF THE SKIN AND EYE WITH PAIN AND BLURRED VISION. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN, LIVER, KIDNEY, OR RESPIRATORY DISEASE MAY BE AT AN INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE SUBJECT TO FRESH AIR, IF BREATHING STOPPED GIVE ARTIFICIAL RESPIRATION. EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WAT ER. INGESTION: INDUCE VOMITING BY PLACING FINGER AT THE BACK OF THE THROAT. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:52.0F,11.1C Autoignition Temp:Autoignition Temp Text:896F Lower Limits:2.4 Upper Limits:8.0 Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR ALCOHOL FOAM Fire Fighting Procedures:MOVE FROM FIRE AREA, IF POSSIBLE. USE FLOODING AMOUNTS OF WATER AS A FOG, SOLID STREAMS MAY BE INEFFECTIVE. AVOID BREATHING VAPORS, KEEP UPWIND. Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST WHEN EXPOSED TO HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR SOAK UP SMALL SPILLS WITH PAPER TOWEL OR INERT ABSORBANT. DIKE TO RETAIN LARGE SPILLS. REMOVE RESIDUE WITH INERT ABSORBANT. PLACE IN DISPOSAL CONTAINER. ISOLATE HAZARD AREA AND DENY ENTRY. NO SMOKING OR OPEN FLAMES IN THE AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT AND IGNITION SOURCES. KEEP CONTAINERS CLOSED. Other Precautions:VAPOR HAZARD INDOORS, OUTDOORS OR IN SEWERS, RUN-OFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) VENTILATION IS REQUIRED. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA IS NOT VENTED. Protective Gloves:RUBBER Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=82.2C, 180.F Melt/Freeze Pt:=25.6C, 78.F Vapor Pres:31 Vapor Density:2.6 Spec Gravity:0.80 Evaporation Rate & Reference:1.05 (BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS, HYGROSCOPIC LIQUID OR CRYSTALS WITH CAMPOR ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS, ALUMINUM, CHROMIUM TRIOXIDE, OXIDIZERS, PLASTICS, MINERAL ACIDS, HYDROCHLORIC ACID. Stability Condition to Avoid:STABLE IN CLOSED CONTAINERS UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:STRONG MINERAL ACIDS OR THERMAL-OXIDATIVE REACTIONS CAUSE DECOMPOSITION & MAY RELEASE CARBON MONOXIDE OR ISOBUTYLENE GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.