SPECTRUM CHEMICAL MFG CORP -- GIEMSA STAIN SOLUTION, 0HS41046 -- 6550-00N089777
===================== Product Identification ===================== Product ID:GIEMSA STAIN SOLUTION, 0HS41046 MSDS Date:11/06/1991 FSC:6550 NIIN:00N089777 Status Code:A === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG CORP Address:14422 SOUTH SAN PEDRO ST City:GARDENA State:CA ZIP:90248 Country:US Info Phone Num:310-516-8000 Emergency Phone Num:800-414-9300(CHEMTREC) CAGE:63415 === Contractor Identification === Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:GLYCERIN. LD50: (ORAL, RAT) 12600 MG/KG. CAS:56-81-5 RTECS #:MA8050000 Fraction by Wt: 61% OSHA PEL:15 MG/M3 (MIST) ACGIH TLV:10 MG/M3 (MIST) Ingred Name:METHYL ALCOHOL (SARA 313) (CERCLA). LD50: (ORAL, RAT) 5628 MG/KG. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 38.3% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM; 250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AZURE II CAS:37247-10-2 Fraction by Wt: 0.16% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AZURE II CAS:53092-85-6 Fraction by Wt: 0.6% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: MILE IN ALL DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK INVOLVED IN FIRE. EXTING ONLY IF FLOW CAN BE STOPPED.(ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: USE FLOODING AMTS OF WATER AS FOG; SOLID STREAMS MAY BE INEFTIVE. COOL CNTNRS W/FLOODING AMTS OF WATER (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: FROM AS FAR A DISTANCE AS POSSIBLE. AVOID BRTHG VAPS; KEEP UPWIND. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: SKIN W/SUBSEQUENT IRRIT & REDNESS. ALLERGIC RXNS RARE BUT MAY OCCUR IN SENSITIVE PERS. METHANOL:(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CNTCT W/LIQ MAY CAUSE IRRIT. ABSORPTION MAY OCCUR & CAUSE METABOLIC ACIDOSIS & EFTS ON EYES & CNS AS WITH (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:ACUTE INGEST. EYE:GLYCERIN:APPLICATN IN HUMAN EYE MAY CAUSE STRONG STING & BURN SENSATION W/REFLEX TEARING(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:& DILATION OF CONJ VESSELS, BUT NO INJURY. INSTILLATION INTO ANTERIOR CHAMBER RSLTD IN INFLAM RXN & EDEMA(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: OF CORNEA W/WRINKLING OF POSTERIOR SURF & DMG OF ENDOTHELIAL CELLS. METHANOL:VAPS MAY CAUSE IRRIT. HIGH (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: CONCS REPORTED TO CAUSE VIOLENT INFLAM OF CONJ & EPITHELIAL DEFECTS ON CORNEA. MILD IRRIT MAY OCCUR WITH(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: DILUTE SOLNS. INGEST:GLYCERIN: 100ML RSLTD IN HDCH, NAUS & VOMIT; DIGEST TRACT IRRIT, INSOM, DIZZ, DIARR(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: & FEVER. LG DOSES MAY CAUSE HEMOLYSIS, HEMOGLOBINURIA, HYPERGLYCEMIA, GLYCOSORIA, CONVLS, RENAL FAILURE,(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: PARALYSIS. MAY LOWER INTRAOCULAR PRESS & CAUSE HYPOVOLEMIA. RPTS OF REPRO EFTS IN ANIMALS. METHANOL:MAY (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: CAUSE MILD & TRANSIENT INEBRIATION & SUBSEQUENT DROW W/ASYMPTOMATIC PERIOD LASTING 8-48 HRS. AFTER DELAY(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: COUGH, DYSPNEA, HDCH, DULLNESS, WEAK, VERTIGO/DIZZ, NAUS, VOMIT, OCCASNL DIARR, ANOREXIA, VIOLENT PAIN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: IN BACK, ABDOMEN & EXTREMITIES, RESTLESSNESS, APATHY/DELIURIM & RARELY EXCITMENT & MANIA. RAPID, SHALLOW(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: RESPIRATION, COLD & CLAMMY SKIN, HYPOTENSION, CYANOSIS, MILD TACHYCARDIA, CARD DEPRESS, CEREBRAL & PULM (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: EDEMA, UNCON, COMA. EYE EFTS:BLINDNESS POSS. CHRONIC: EFTS AS IN ACUTE INGEST. SKIN:ERYTHEMA, SCALES & (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: ECZEMATOID DERM. METABOLIC ACIDOSIS. EYES:CONJ. INGEST:VISUAL IMPAIRMENT. CONTACT NEHC FOR MORE INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: UNTIL NO EVID OF CHEM REMAINS (AT LST 15-20 MIN). GET MED ATTN IMMED. INGEST:TREAT SYMP & (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: SUPPORTIVELY. GET MED ATTN & ADVICE ON WHETHER TO USE GASTRIC LAVAGE. USE EXTREME CARE TO PVNT ASPIR. (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24: CUFFED ENDOTRACHEAL TUBE USED BY QUALIFIED MED PERS MAY BE ADVISIBLE. KEEP HEAD LOWER THAN HIPS TO PVNT ASPIR. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:NOT LIKELY HAZ AT NORM ROOM TEMPS. VAP/MIST IN SUFFICIENT CONCS MAY INTERFERE W/RESP FUNC. AT ELEVATED TEMPS FUME MAY CAUSE IRRIT & DEHYDRATION OF MUC MEMBS. METHANOL: NARCOTIC/NEUROTOXIN. 25,000 PPM IDLH. MAY CAUSE MUC MEMB IRIT, COUGH, OPRESSION IN CHEST, TRACHEITIS, BRONCH, TINNITUS, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: UNSTEADY GAIT, TWITCH, COLIC, CONSTIP, NYSTAGMUS & BLEPHAROSPASM. OCCUP EXPOS SYMPS INCL PARESTHESIAS, NUMB & SHOOTING PAINS IN HANDS & FOREARMS. METABOLIC ACIDOSIS & EYE & CNS EFTS MAY OCCU R AS W/INGEST. SKIN:APPLICATN OF CONCENTRATED GLYCERIN MAY CAUSE EFTS RANGING FROM MILD IRRIT TO DEHYDRATION OF (ING 8) Medical Cond Aggravated by Exposure:AT INCREASED RISK FROM EXPOSURE: PERSONS WITH KIDNEY, EYE OR SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPS PERFORM ARTF RESP. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP OR MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORM SALINE, OCCASNLY LIFTING UPPER & LOWER LIDS (ING 23) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:61.0F,16.1C Extinguishing Media:DRY CHEM, CARBON DIOXIDE, WATER SPRAY/ALCOHOL-RESIST FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG/ALCOHOL-RESIST FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM AREA IF YOU CAN DO IT W/OUT RISK. APPLY COOLING WATER TO SIDES OF CNTNRS EXPOS TO FLAMES(SUPDAT) Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOS TO HEAT/FLAME. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO IGNIT SOURCE & FLASH BACK. VAP-AIR MIXS EXPLOSIVE AVOVE FL PT. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF YOU CAN W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SM SPILL:TAKE UP W/ABSORB MATL; PLACE INTO CNTNRS FOR DISP. LG SPILL:DIKE AHEAD FOR LATER DISP. NO SMKNG, FLAME S, FLARES. KEEP UNNEC PERS AWAY. ISOLATE AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH HEAT, SPARKS, FLAMES OR OTHER SOURCES OF IGNTION. VAPORS MAY BE EXPLOSIVE AND POISONOUS; DO NOT ALLOW UNNECESSARY PERS IN AREA. Other Precautions:DO NOT OVERHEAT CONTAINERS; CONTAINERS MAY VIOLENTLY RUPTURE AND TRAVEL A CONSIDERABLE DISTANCE IN HEAT OF FIRE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, BE BASED ON SPECIFIC OPERATION, MUST NOT EXCEED WORKING LIMS OF RESP & MUST BE NIOSH APPRVD. CONTACT NEHC FOR A LIST OF RECOM MENDED RESPIRATORS . Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENT TO MEET PUBLISHED EXPOS LIMITS. VENT EQUIP MUST BE EXPLOSION-PROOF. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . APPROP PROT (IMPERVIOUS) CLTHG TO PVNT RPTD/PRLNGD CNTCT W/SUBSTANCE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZS; IF IMPOSS, W/DRAW FROM AREA & LET FIRE BURN. W/DRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1/2 (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>147F,>64C Solubility in Water:COMPLETE Appearance and Odor:LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES GLYCERIN: CHROMIUM TRIOXIDE, STRONG OXIDIZERS. METHYL ALCOHOL: CHLORINE, LEAD. CNTCT NEHC FOR A COMPLETE LIST . Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.