FISHER SCIENTIFIC -- ZINC OXIDE, Z0228 -- -
===================== Product Identification ===================== Product ID:ZINC OXIDE, Z0228 MSDS Date:12/12/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:ONE REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 Resp. Party Other MSDS Num.:ACC 25490 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC OXIDE (ZNO); (ZINC OXIDE) EINECS/ELINCS: 215-222-5. CAS:1314-13-2 RTECS #:ZH4810000 = Wt:100. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:5 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: DUST MAY CAUSE MECHANICAL IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MODERATELY TOXIC TO HUMANS BY INGESTION. INHALATION: EFFECTS MAY BE DELAYED. INHALATION OF FUMES MAY CAUS E METAL FUME FEVER, WHICH IS CHARACTERIZED BY FLU-LIKE SYMPTOMS WITH METALLIC TASTE, FEVER, CHILLS, COUGH, WEAKNESS, CHEST PAIN, MUSCLE PAIN AND INCREASED WHITE BLOOD CELL COUNT. ZINC OXIDE DUST IS CO NSIDERED TO BE OF LOW TOXICITY AND IS CLASSIFIED AS A NUISANCE PARTICULATE BY THE ACGIH. HOWEVER, INHALATION OF FUMES OR VERY FINE DUST MAY CAUSE "ZINC FUME FEVER", WHICH IS CHARACTERIZED BY FLU-LIKE SYMPTOMS WITH (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT LISTED. Effects of Overexposure:HEALTH HAZARDS: METALLIC TASTE, COUGHING, WEAKNESS, FATIGUE, MUSCULAR PAIN, AND NAUSEA, FOLLOWED BY FEVER AND CHILLS. ONSET OF SYMPTOMS OCCURS ABOUT 4-12 HOURS AFTER EXPOSURE. CHRONIC: NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID. SKIN: GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MIN UTES, WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR IMM EDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: THE ONSET OF SYMPTOMS MAY OCCUR 4-12 HOURS AFTER EXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NON-COMBUSTIBLE; USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID BREATHING DUST, VAPOR, MIST, OR GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. STORE IN A DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:APPROPRIATE PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Supplemental Safety and Health MOLECULAR FORMULA: ZNO. FED REGS: OSHA: NONE OF CHEMS IN PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS: EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZ SYMBOLS: NOT AVAIL. WGK (WATER DANGER/PROT): CAS # 1314-13-2: 0. CANADA: CAS # 1314-13-2 IS LISTED ON CANADA'S DSL/NDSL LIST. (ECOL INFO) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=1800.C, ######F Spec Gravity:5.68 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE TO YELLOW-WHITE SOLID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS EXPLOSIVELY WITH MAGNESIUM WHEN HEATED. MIXTURES OF CHLORINATED RUBBER AND ZINC OXIDE CAN EXPLODE VIOLENTLY WHEN HEATED TO 419F. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:TOXIC FUMES OF ZINC OXIDE. =================== Toxicological Information =================== Toxicological Information:RTECS #: CAS # 1314-13-2: ZH4810000. LD50/LC50: INHALATION, MOUSE: LC50 = 2500 MG/M3. ORAL, MOUSE: LD50 = 7950 MG/KG. EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY, O THER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, OTHER: NO INFO FOUND. --SUPDAT: PROD HAS A WHMIS CLASSIFICATION OF D2B. PROD IS NOT LISTED ON CANADA'S ING DISCLOSURE LIST. EXPOS LIMS: OEL-ARAB REP UBLIC OF EGYPT: TWA 5 MG/M3. OEL-AUSTRALIA: TWA 10 MG/M3. OEL-AUSTRALIA: TWA 5 MG/M3; STEL 10 MG/M3 (FUME). OEL-BELGIUM: TWA 10 MG/M3. OEL-BELGIUM: TWA 5 MG/M3; STEL 10 MG/M3 (FUME) JAN9. OEL-CZECHOSL OVAKIA: TWA 5 MG/M3; STEL 15 MG/M3 JAN9. OEL-DENMARK: TWA 4 MG/M3 (FUME). OEL-DENMARK: TWA 4 MG/M3 (DUST). OEL-FINLAND: TWA 5 MG/M3 (FUME). OEL-FRANCE: TWA 10 MG/M3. OEL-FRANCE: TWA 5 MG/M3 (FUME). OE L-GERMANY: TWA 5 MG/M3 (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LI STED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFORMATION AVAILABLE. --ECOL INFO: (FUME). OEL-HUNGARY: TWA 5 MG/M3. OEL-JAPAN: TWA 5 MG/M3 (FUME). OEL-THE NETHERLANDS: TWA 5 MG/M3. OEL-THE PHILIPPINES: TWA 1 MG/M3. OEL-POLAND: TWA 4 MG/M3 (FUME). OEL-SWEDEN: TWA 5 MG/M3. OEL-SWITZERLAND: TWA 5 MG/M3. OEL-SWITZERLAND: TWA 5 MG/M3 (FUME). OEL-THAILAND: TWA 5 MG/M3 (FUME). OEL-TURKEY: TWA 5 MG/M3. OEL- UNITED KINGDOM: TWA 5 MG/M3; STEL 10 MG/M3 JAN9. OEL-UNITED KINGDOM: TWA 5 MG/M3; STEL 10 MG/M3 (FUME). OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA, NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 1314-13-2: ACUTE. SECTION 313: THIS MATERIAL CONTAINS ZINC OXIDE (LISTED AS ZINC), 100%, (CAS # 1314-13-2) WHICH IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR PART 373. Federal Regulatory Information:TSCA: CAS # 1314-13-2 IS LISTED ON TSCA INVENTORY. HLTH & SFTY REPORTING LIST: NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. SECTION 12B: NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS, ANY CLASS 1 OZONE DEPLETORS/ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES, PRIORITY POLLUTANTS/TOX POLLUTANTS UNDER CWA. (SUP DAT) State Regulatory Information:CAS # 1314-13-2 CAN BE FOUND ON THE FOLLOWING STATE RIGHT-TO-KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEM ICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.