WARDS NATURAL SCIENCE ESTABLISHMENT INC -- MALEIC ACID -- 6810-00D020102
===================== Product Identification ===================== Product ID:MALEIC ACID MSDS Date:09/30/1992 FSC:6810 NIIN:00D020102 === Responsible Party === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692 Country:US Info Phone Num:716-334-4222 716-359-2502 Emergency Phone Num:716-226-6177 800-424-9300(CHEMTREC) Preparer's Name:ALEXANDER A. PICCIRILLI CAGE:63759 === Contractor Identification === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:MALEIC ACID (CERCLA) CAS:110-16-7 RTECS #:OM9625000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 708MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES:CORROSIVE.MAY CAUSE IRRITATION,POSSIBLE CORNEAL EROSION.SKIN:MAY CAUSE IRRITATION AND DERMATITIS.INGEST:MODERATELY TOXIC.MAY BE FATAL IF SWALLOWED.MAY CAUSE GI TRACT IRRITATION.MAY DAMAGE MOUTH,E SOPHAGUS AND STOMACH.INHAL:MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:DIFFICULTY BREATHING,COUGHING.EYES:REDNESS,PAIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.GET MEDI CAL ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE 1-2 GLASSES OF WATER OR MILK. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY,DRY CHEMICAL(ABC),CARBON DIOXIDE,HALON,STANDARD FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:SUBLIMES AT 396F;EMITS FUMES UPON HEATING.DECOMPOSITION FUMES MAY BE TOXIC.REACTS VIGOROUSLY WITH OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER IF NOT CONTAMINATED.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SWEEP OR VACUUM;DO NOT CREATE DUST;PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL.FLUSH SPILL AREA WITH WATER.DO NOT POLLUTE WATERWAYS WITH RINSEATE. Neutralizing Agent:NOT REPORTED. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:AVOID SKIN AND EYE CONTACT.DO NOT INHALE VAPORS/MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR DUST. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Protective Gloves:RUBBER. Eye Protection:CHEMICAL SAFETY GLASSES. Other Protective Equipment:SMOCK,APRON.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:268F,131C Decomp Temp:Decomp Text:275F,135C Vapor Pres:NEGLIGIBLE Vapor Density:4.0 Spec Gravity:1.59 Evaporation Rate & Reference:NON-VOLATILE Solubility in Water:APPRECIABLE Appearance and Odor:WHITE CRYSTALLINE POWDER;FAINT ACIDULOUS ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,ALKALI METALS,STRONG BASES,AMINES.SOLUTIONS OF MALEIC ACID MAY CORRODE METAL. Stability Condition to Avoid:AT 230C,IT CONVERTS TO FUMARIC ACID AND UNDERGOES PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE. Hazardous Decomposition Products:AT 230C,CONVERTS TO FUMARIC ACID AND UNDERGOES PARTIAL CARBONIZATION AND FORMATION OF MALEIC ANHYDRIDE(READILY SUBLIMES) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.MAY BE INCINERATED. 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