MATHESON TRI-GAS, INC. -- TETRAFLUOROETHYLENE -- -
===================== Product Identification ===================== Product ID:TETRAFLUOROETHYLENE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:TETRAFLUOROETHYLENE CAS:116-14-3 Fraction by Wt: 99% Ingred Name:INHIBITORS Fraction by Wt: 1% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: sore throat, nausea, vomiting, asthma, headache, suffocation, lung congestion, convulsions, coma LONG TERM EXPOSURE: kidney damage SKIN CONTACT: SHORT TERM EXPOSURE: no information on significant adverse effects LONG TERM EXPOSURE: no information on significant adverse effects EYE CONTACT: SHORT TERM EXPOSURE: irritation, tearing, difficulty breathing LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: no information on significant adverse effects LONG TERM EXPOSURE: no information on significant adverse effects Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If a large amount is swallowed, get medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. ===================== Fire Fighting Measures ===================== Flash Point:flammable Autoignition Temp:392 F (200 C) Lower Limits:10% Upper Limits:50% Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Stop leak if possible without personal risk. Let burn unless leak can be stopped immediately. For smaller tanks or cylinders, extinguish and isolate from other flammables. Evacuation radius: 800 meters (1/2 mile). Unusual Fire/Explosion Hazard:Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. ================== Accidental Release Measures ================== Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Protect from physical damage. Store in a well-ventilated area. Store outside or in a detached building. Avoid contact with light. Keep separated from incompatible substances. Provide fire protection and spill control systems suitable for the hazards of the material. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health TETRAFLUOROETHYLENE: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:-105 F (-76 C) Melt/Freeze Pt:-224 F (-142 C) Vapor Pres:Not available Vapor Density:3.9 Spec Gravity:1.5 pH:Not applicable Evaporation Rate & Reference:Not applicable Solubility in Water:insoluble Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:odorless Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:May explode when heated. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: halogenated compounds, acid halides Thermal decomposition products: halogenated compounds, acid halides Conditions to Avoid Polymerization:Polymerizes with evolution of heat. Monitor inhibitor content. =================== Toxicological Information =================== Toxicological Information:TETRAFLUOROETHYLENE: TOXICITY DATA: 40000 ppm/4 hour(s) inhalation-rat LC50 LOCAL EFFECTS: Irritant: eye ACUTE TOXICITY LEVEL: Slightly Toxic: inhalation TUMORIGENIC DATA: Available. REPRODUCTIVE EFFECTS DATA: Available. ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Tetrafluoroethylene, inhibited ID NUMBER: UN1081 HAZARD CLASS OR DIVISION: 2.1 LABELING REQUIREMENTS: Flammable gas QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: 150 kg ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: Yes SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): TETRAFLUOROETHYLENE: 5000LBSTQ State Regulatory Information: California Proposition 65: Known to the state of California to cause the following: TETRAFLUOROETHYLENE Cancer (May 01, 1997) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.