DOW CHEMICAL U S A -- ORTHO-DICHLOROBENZENE REFINED -- 6810-00F000069
===================== Product Identification ===================== Product ID:ORTHO-DICHLOROBENZENE REFINED MSDS Date:05/21/1979 FSC:6810 NIIN:00F000069 === Responsible Party === Company Name:DOW CHEMICAL U S A Address:2030 DOW CTR City:MIDLAND State:MI ZIP:48674 Country:US Info Phone Num:517-636-4400 Emergency Phone Num:517-636-4400 CAGE:71983 === Contractor Identification === Company Name:DOW CHEMICAL U.S.A. City:MIDLAND State:MI ZIP:48674 Country:US Phone:517-636-4400 CAGE:71983 ============= Composition/Information on Ingredients ============= Ingred Name:O-DICHLOROBENZENE, 1,2-DICHLOROBENZENE (ORTHO) CAS:95-50-1 RTECS #:CZ4500000 Fraction by Wt: 98% Other REC Limits:50 PPM OSHA PEL:C 50 PPM ACGIH TLV:S, 25PPM/50 STEL9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:P-DICHLOROBENZENE, 1,4-DICHLOROBENZENE (PARA); BENZENE, P-DICHLORO; PARADICHLORBENZENE CAS:106-46-7 RTECS #:CZ4550000 Fraction by Wt: 2% Other REC Limits:75 PPM A2 CARCINOGEN OSHA PEL:75 PPM ACGIH TLV:10 PPM,A3 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL (RAT): 500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: PAIN, SLIGHT IRRITATION. SKIN: BURNING SENSATION. MODERATE IRRITATION. ABSORPTION BUT HAS LOW DEGREE OF TOXICITY. INHALATION: RESPIRATORY PASSAGES IRRITATION, CNS DEPRESSION, POSSIBLE LIVER & KI DNEY INJURY. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN ABSORPTION: TOXIC UPON EXCESSIVE & SEVERE EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF RESPIRATION STOPS GIVE MOUTH-TO-MOUTH RESUSCITATION. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTEN TION IN ALL CASES. NOTE TO PHYSICIAN: EYES: STAIN FOR EVIDENCE OF CORNEAL INJURY. SKIN: TREAT AS ANY CONTACT DERMATITIS. INHALATION: BRONCHODILATORS, EXPECTORANTS & ANTITUSSIVES MAY HELP. SEE SUPP. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:160F Lower Limits:2.2% Upper Limits:9.2% Extinguishing Media:WATER FOG, FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. PUMP LARGE AMOUNT INTO CONTAINERS. COVER RESIDUE AND SMALL SPILLS W/ABSORBENT MATERIAL AND SCOOP INTO DRUMS. ====================== Handling and Storage ====================== Other Precautions:AVOID SKIN & EYE CONTACT & THE INHALATION OF VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR. FOR EMERGENCIES, USE A SELF CONTAINED BREATHING APPARATUS OR A FULL FACE RESPIRATOR AS APPROVED BY NIOSH. Ventilation:RECOMMEND CONTROL OF VAPORS TO SUGGESTED GUIDE. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GLASSES W/OUT SIDE SHIELDS Other Protective Equipment:CLEAN, BODY COVERING CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DESTROY CONTAMINATED SHOES. Supplemental Safety and Health CON'T: INGESTION: MAY CAUSE CHEMICAL PNEUMONIA IF ASPIRATED INTO LUNGS. DANGER OF CHEMICAL PNEUMONIA MUST BE WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH. IF LAVAGE IS PERFORMED SUGG EST ENDOTRACHEAL &/OR ESOPHAGOSCOPIC CONTROL. NO SPECIFIC ANTIDOTE. PRODUCT DISCONTINUED IN 1984. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:356F/108C Vapor Pres:1.2 Vapor Density:5.1 Spec Gravity:1.303 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, CHARACTERISTIC LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM AND ALUMINUM ALLOYS Hazardous Decomposition Products:HYDROGEN CHLORIDE AND CHLORINE ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS OR CALL THE DOW CHEMICAL COMPANY FOR INSTRUCTIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.