ANACHEMIA CANADA -- POTASSIUM CHROMATE -- 6810-00-985-7092
===================== Product Identification ===================== Product ID:POTASSIUM CHROMATE MSDS Date:11/03/1998 FSC:6810 NIIN:00-985-7092 Status Code:A === Responsible Party === Company Name:ANACHEMIA CANADA Address:255 NORMAN H8R 1A3 City:VILLE ST. PIERRE (MONTREAL) State:PQ Country:CN Info Phone Num:514-489-5711 Emergency Phone Num:613-996-6666/518-297-4444 Chemtrec Ind/Phone:(800)424-9300 CAGE:36842 === Contractor Identification === Company Name:ANACHEMIA Address:3 LINCOLN BLVD Box:City:ROUSES POINT State:NY ZIP:12979 Country:US Phone:518-297-4444 CAGE:HO801 Company Name:ANACHEMIA CANADA Address:255 NORMAN H8R 1A3 Box:City:VILLE ST. PIERRE (MONTREAL) State:PQ Country:CN Phone:514-489-5711;518-297-4444 CAGE:36842 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM CHROMATE CAS:7789-00-6 RTECS #:GB2940000 Minumum % Wt:90. Maxumum % Wt:100. Other REC Limits:SEE OTHER INFO. OSHA PEL:0.1MG(CRO3)M3 CEIL ACGIH TLV:0.05 MG(CR)/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL SECTION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF ACUTE EXPOSURE: MAY BE FATAL BY INGESTION, INHALATION, SKIN ABSORPTION. SEVERE IRRITANT! 30 MG/M3 IS IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. POTENTIALLY HARMFUL AMOUNTS CAN CAUSE DAMAGE TO KIDNEYS, LIVER, BLOOD, LUNG, EYE, SKIN, RESPIRATORY SYSTEM &/OR BONE MARROW. EYE: CAUSES CONJUNCTIVITIS, SEVERE IRRITATION OR BURNS & LOSS OF VISION. MAY CAUSE PERMANENT DAMAGE. SKIN: CAUSES SEVERE I RRITATION & BLISTERS ON CONTACT W/SKIN. PROLONGED EXPOSURE MAY RESULT IN SKIN BURNS & ULCERATIONS. CONTACT W/BROKEN SKIN MAY LEAD TO FORMATION OF FIRMLY MARGINATED "CHROME SORES". MASSIVE OVEREXPOSURE COULD (SIGNS/SYMPS OF OVEREXPOSURE) Explanation of Carcinogenicity:POTASSIUM CHROMATE: IARC GROUP 1, VOLUME 49, PAGE 49, 1990 . Effects of Overexposure:ACUTE/CHRONIC (CONT'D): LEAD TO DAMAGE TO KIDNEYS, LIVER, BLOOD AND/OR BONE MARROW, KIDNEY FAILURE AND DEATH. A STRONG SENSITIZER WHICH MAY CAUSE SKIN RASH. INHALATION: DUST OR MIST MAY IRRITATE NASAL SEPTUM & RESPIRATORY TRACT. DESTRUCTIVE TO TISSUES OF MUCOUS MEMBRANES. PROLONGED/REPEATED EXPOSURE MAY CAUSE ULCERATION & PERFORATION OF NASAL SEPTUM. MAY CAUSE HEADACHE, NAUSEA, VOMITING, CHEMICAL PNEUMONITIS & PULMONARY EDEMA. MAY CAUSE SENSITIZATION BY INHALATION. CAN CAUSE LIVER, KIDNEY & LUNG DAMAGE. INGESTION: BURNS IN MOUTH, PHARYNX & GASTROINTESTINAL TRACT (CAN CAUSE SEVERE TISSUE DESTRU CTION). MAY CAUSE VOMITING, (STATE REGS) Medical Cond Aggravated by Exposure:N/P. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES, HOLDING LIDS APART TO ENSURE FLUSHING OF ENTIRE SURFACE. CALL PHYSICIAN. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN, WHILE REMOVING CONTAMINATED CLOTHING/SHOES. SEEK IMMEDIATE MEDICAL ATTENTION. WASH CONTAM CLOTHING BEFORE REUSE. DISCARD CONTAM LEATHER ARTICLES SUCH AS BELTS & SHOES. INHA LATION: REMOVE PATIENT TO FRESH AIR. ADMINISTER APPROVED OXYGEN SUPPLY IF BREATHING DIFFICULT. ADMINISTER ARTIFICIAL RESPIRATION OR CPR IF BREATHING HAS CEASED. SEEK IMMEDIATE MEDICAL ATTENTION. (SUP PL SAFETY/HEALTH) ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NOT AV Lower Limits:NOT AVAILABL Upper Limits:NOT AVAILABL Extinguishing Media:USE FLOODING QUANTITIES OF WATER. COOL CONTAINING VESSELS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. Fire Fighting Procedures:WEAR ADEQUATE PERSONAL PROTECTION TO PREVENT CONTACT WITH MATERIAL OR ITS COMBUSTION PRODUCTS. NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. DO NOT ENTER CONFINED FIRE SPACE WITHOUT ADEQUATE PROTECTIVE CLOTHING & APPROVED SCBA. Unusual Fire/Explosion Hazard:POWERFUL OXIDIZING AGENT: MAY IGNITE OXIDIZABLE MATERIAL. CONTRIBUTES TO COMBUSTION OF OTHER MATERIAL. CONTACT WITH OTHER MATL MAY CAUSE FIRE/EXPLOSION. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDIT IONS OR WHEN HEATED. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. FIRE DEGRADATION PRODUCTS: OXIDES OF CHROMIUM & POTASSIUM. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS, HEAVY RUBBER GLOVES. FULL SUIT. EVACUATE AREA. ELIMINATE ALL SOURCES IGNITION. SWEEP UP & PLACE IN CONTAINER FOR DISPOSAL. AVOID RAISING DUST. US E NON-SPARKING TOOLS. VENT AREA, WASH SPILL SITE AFTER MATERIAL PICKUP COMPLETE. DO NOT EMPTY INTO DRAIN OR TOUCH SPILLED MATL. AVOID CONTACT WITH COMBUSTIBLE MATERIAL (WOOD, PAPER, OIL, CLOTHES). ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL WELL VENTILATED AREA AWAY FROM HEATED AREAS, SPARKS & FLAMES. STORE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT ADD ANY OTHER MATERIAL TO CONTAINER. DO NOT WASH DOWN THE DRAIN. DO NOT BRE ATHE DUST. KEEP CONTAINER TIGHTLY CLOSED & DRY. MANIPULATE UNDER ADEQUATE FUME (OTHER PRECAUTIONS) Other Precautions:HANDLING/STORAGE (CONT'D): HOOD. AVOID RAISING DUST. HANDLE & OPEN CONTAINER WITH CARE. MINIMIZE DUST GENERATION & EXPOSURE-USE DUST MASK OR APPROPRIATE PROTECTION. THIS PRODUCT MUST BE MANIPULATED BY QUALIFIED PERSONNEL. PRODUCT IS HIGHLY HYGROSCOPIC. DO NOT STORE ON WOOD FLOORS. KEEP AWAY FROM COM BUSTIBLE (TRANSPORT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH-APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROLS. IF MORE THAN TLV, DO NOT BREATHE VAPOR. SUPP SAFETY (CONTD): SEEK IMMED IATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Ventilation:USE ONLY IN CHEMICAL FUME HOOD TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. DO NOT USE IN UNVENTILATED SPACES. Protective Gloves:IMPERVIOUS RUBBER GLOVES . Eye Protection:ANSI-APPROVED CHEMICAL SAFETY GOGGLES & FULL FACESHIELD . Other Protective Equipment:PROTECTIVE CLOTHING: IMPERVIOUS APRON, COVERALLS &/OR OTHER RESISTANT PROTECTIVE CLOTHING TO PROTECT SKIN. SUFFICIENT TO PROTECT SKIN. MAKE EYE BATH & EMERGENCY SHOWER AVAILABLE PROXIMAL TO WORKSTATION. Work Hygienic Practices:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. WASH WELL AFTER USE. DO NOT ALLOW SMOKING AND FOOD CONSUMPTION WHILE HANDLING. DO NOT WEAR CONTACT LENSES. WEAR CLEAN WORK CLOTHING DAILY. Supplemental Safety and Health FIRST AID (CONT'D):INGEST: IF CONSCIOUS, WASH OUT MOUTH WITH WATER. HAVE CONSCIOUS PERSON DRINK SEVERAL GLASSES WATER TO DILUTE. INDUCE VOMITING BY EITHER GIVING IPECAC SYRUP OR PLACING FINGER AT BACK OF THROAT. VOMITING SHOULD ONLY BE INDUCED UNDER DIRECTION OF PHYSICIAN/POISON CONTROL CENTER. (RESPIRATORY PROTECTION) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=975.C, ######F Vapor Pres:NOT AVAILABLE Vapor Density:6.7(AIR=1) Spec Gravity:2.73 (WATER=1) pH:8.6-9.8(5%,25C) Solubility in Water:SOLUBLE IN WATER. Appearance and Odor:SOLID YELLOW CRYSTALS; ODORLESS. Percent Volatiles by Volume:0% @ 21C ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, REDUCING MATERIALS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, METALS, ALKALIES, ALCOHOLS, ACETONE, HYDRAZINE, HYDROXYLAMINE, HYDROXYLAMINE SALTS, MERCURY CYANIDE, CALCIUM HYDROXIDE, ETHYLENE GLYCOL, OILS, GREA Stability Condition to Avoid:STABLE. CONDITIONS TO AVOID: HIGH TEMPERATURES, SPARKS, OPEN FLAMES AND ALL OTHER SOURCES OF IGNITION, CONTAMINATION. Hazardous Decomposition Products:NOT AVAILABLE. REACTION PRODUCTS: CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE AND/OR EXPLOSION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TOXICITY VALUES OF HAZARDOUS INGREDIENTS: POTASSIUM CHROMATE: ORAL (LD50): ACUTE: 180 MG/KG (MOUSE). INTRAPERITONEAL (LD50): ACUTE: 32 MG/KG (MOUSE). INTRAMUSCULAR (LD50): ACUTE: 11 MG/KG (RABBIT). MA TERIALS TO AVOID (CONT'D): OXIDIZING AGENTS, EASILY OXIDIZABLE MATERIALS, CARBIDES, SULFUR, ALUMINUM, SULFURIC ACID, BORON, SILICON, ACETIC ANHYDRIDE, AMINES, PAPER, WOOD, SULFUR. THIS PRODUCT IS MILD OXIDIZER IN SOLUTION, BUT A STRONG OXIDIZER IN HIGHLY ACIDIC SOLUTIONS.SPECIAL PREC/COMMENTS: POWERFUL OXIDIZING AGENT; MAY IGNITE OXIDIZABLE MATLS. HIGHLY TOXIC! CARCINOGEN! MUTAGEN! SEVERE IRRITANT ! CONTACT NEHC FOR ADDITIONAL INFO. ===================== Ecological Information ===================== Ecological:N/P. STATE REGULATIONS (CONT'D): SUBSTANCE KNOWN TO CAUSE ALLERGIC REACTIONS IN CERTAIN INDIVIDUALS ONCE THEY BECOME SENSITIZED AFTER EXPOSURE TO EVEN SMALL AMOUNTS OVER PERIOD OF TIME. CHROMIUM (VI) COMPOUNDS IN FORM OF CHROMATES & DICHROMATES HAVE BEEN FOUND TO BE MUTAGENIC IN BACTERIAL & MAMMALIAN CELLS, INCLUDING THOSE OF CHINESE HAMSTER. PASSES THROUGH PLACENTAL BARRIER IN ANIMAL. TO THE BEST OF CO.'S KNOWLEDGE, CHEMICAL, PHYSICAL & TOXICITY OF SUBSTANCE HAS NOT BEEN FULLY INVESTIGATED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE TO ALL FEDERAL STATE AND LOCAL REGULATIONS . ACCORDING TO ALL APPLICABLE REGULATIONS. HARMFUL TO AQUATIC LIFE AT VERY LOW CONCENTRATIONS. CAN BE DANGEROUS IF ALLOWED TO ENT ER DRINKING WATER INTAKES. DO NOT CONTAMINATE DOMESTIC OR IRRIGATION WATER SUPPLIES, LAKES, STREAMS, PONDS OR RIVERS. =================== MSDS Transport Information =================== Transport Information:TDG ROAD/RAIL: TDG CLASS: 9.2. PIN: NA9142 (RL-50). PG: III. OTHER PRECAUTIONS (CONT'D): MATERIAL. KEEP AWAY FROM DIRECT SUNLIGHT OR STRONG INCANDESCENT LIGHT. EMPTY CONTAINERS MAY CONTAIN A HAZARDOUS RESIDUE. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. USE NON-SPARKING TOOLS. AVOID CONTACT WITH A COMBUSTIBLE MATERIAL (WOOD, PAPER, OIL, CLOTHING...). INSUFFICIENT VENTILATION, WEAR SUITABLE RE SPIRATORY EQUIPMENT. ===================== Regulatory Information ===================== SARA Title III Information:OTHER INFO (CONT'D): PROLONGED EXPOSURE MAY RESULT IN SKIN BURNS & ULCERATIONS. CARCINOGEN! MUTAGEN! SENSITIZER! POSSIBLE RISKS OF IRREVERSIBLE EFFECTS. TOXIC EFFECTS MAY BE DELAYED DO NOT BREATHE DU ST. AVOID ALL CONTACT WITH PRODUCT & PROLONGED/REPEATED EXPOSURE. USE ONLY IN CHEMICAL FUME HOOD. KEEP AWAY FROM HEAT, SPARKS & FLAME. USE NON-SPARKING TOOLS. WHEN CONTAMINATED, VERY SENSITIVE. CONTAC T WITH OTHER MATERIAL MAY FORM SHOCK, HEAT OR FRICTION-SENSITIVE MIXTURES. HANDLE & OPEN CONTAINER WITH CARE. CONTAINER SHOULD BE OPENED ONLY BY TECHNICALLY QUALIFIED PERSON. (FED REG) Federal Regulatory Information:WHMIS: WHMIS CLASS: C D-1B D-2A. SARA (CONT'D): NOTE TO PHYSICIAN: MASSIVE OVEREXPOSURE COULD LEAD TO KIDNEY FAILURE & DEATH. DEATH HAS BEEN AVOIDED IN SEVERAL SUCH CASES THRU USE OF EARLY RENAL DIAL YSIS. IT HAS BEEN REPORTED THERE IS LITTLE VALUE FROM CHELATING AGENTS, HOWEVER, THAT ASORBIC ACID ADMINISTERED INTRAVENOUSLY IS EFFECTIVE ANTIDOTE IN PREVENTING RENAL FAILURE. SKIN ULCERS MAY BE TREA TED BY REMOVAL FROM EXPOSURE, DAILY CLEANSING & DEBRIDEMENT, & APPLICATION OF ANTIBIOTIC CREAM & DRE SSING. State Regulatory Information:N/P.SIGNS/SYMPTS OF OVEREXPOSURE (CONT'D): NAUSEA, ABDOMINAL PAIN, DIARRHEA, COMA, BLEEDING AND/OR TISSURE ULCERATION, GASTROENTRITIS, TOXIC NEPHRITIS, BLOOD AND BONE MARROW DAMAGE, LIVER AND KIDNEY F AILURE, PERIPHERAL VASCULAR COLLAPSE AND DEATH. EFFECTS OF CHRONIC OVEREXPOSURE: DERMATITIS, CONJUNCTIVITIS, "CHROME SORES", ULCERATION & PERFORATION OF NASAL SEPTUM, CHRONIC BRONCHITIS, BRONCHOPNEUMO NIA, PNEUMOCONIOSIS, RHINITIS, EMPHYSEMA, GASTROINTESTINAL DISTURBANCES. THERE IS SUFFICIENT CARCINO GENICITY OF SUBSTANCE IN HUMANS (KNOWN CARCINOGEN). (ECOLOGICAL) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.