ARC CHEMICAL DIV BALCHEM CORP. -- ETHYLENE OXIDE -- 6830-00-291-5007
===================== Product Identification ===================== Product ID:ETHYLENE OXIDE MSDS Date:12/15/1992 FSC:6830 NIIN:00-291-5007 === Responsible Party === Company Name:ARC CHEMICAL DIV BALCHEM CORP. Address:RTE 6 & 284 Box:180 City:SLATE HILL State:NY ZIP:10973 Country:US Info Phone Num:914-355-2891 914-355-6314(FAX) Emergency Phone Num:914-355-2891 800-424-9300(CHEMTREC) Preparer's Name:GEORGE VAIL CAGE:BALCH === Contractor Identification === Company Name:ARC CHEMICAL DIV BALCHEM CORP. Address:RTE 6 & 284 Box:180 City:SLATE HILL State:NY ZIP:10973 Country:US Phone:914-355-2891 800-424-9300(CHEMTREC) CAGE:BALCH ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2; 9495 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 72 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE IRRITATION,CORNEAL INJURY(POSSIBLY PERMANENT).SKIN:LIQUID MAY CAUSE FROSTBITE AND SEVERE IRRITATION.MAY BE DERMALLY ABSORBED IN HARMFUL AMOUNTS.INGEST:MAY CAUSE SEVERE GI TRACT I RRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND CNS DEPRESSION.CHRONIC:SEE SUPPL DATA. Explanation of Carcinogenicity:CONTAINS E [75-21-8] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:SKIN:(REACTIONS MAY BE DELAYED)BLISTERING,BURNS,EDEMA,VESCICLE FORMATION,SEVERE DERMATITIS.SKIN ABSORPTION:HEADACHE,DIZZINESS,NAUSEA,VOMITING.INHAL:HEADACHE,VOMITI NG,CYANOSIS,DROWSINESS,WEAKNESS,INCOO RDINATION,SALIVATION,LABORED BREATHING.INGEST:(UNLIKELY ROUTE OF ENTRY)ABDOMINAL PAIN,NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN,LIVER,KIDNEY,ADRENAL,NERVE OR RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.GET MEDI CAL ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<0F,<-18C Autoignition Temp:Autoignition Temp Text:804F Lower Limits:3 Upper Limits:100 Extinguishing Media:SMALL FIRES:CARBON DIOXIDE,DRY CHEMICAL.LARGER FIRES:POLYMER OR ALCOHOL FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG.FLUSH AREA WITH WATER AFTER FIRE EXTINGUISHED Unusual Fire/Explosion Hazard:**FLAMMABLE - EXPLOSIVE** FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:**ETHYLENE OXIDE GAS LEAK IS AN EMERGENCY** USE PROPER RESIRATORY AND PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF IGNITION.EVACUATE AREA.CALL 800-424-9300(CHEMTREC). Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:DO NOT WEAR CONTACT LENSES.AVOID BREATHING VAPORS.AVOID SKIN AND EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS. Ventilation:USE EXPLOSION-PROOF LOCAL EXHAUST(LABORATORY FUME HOOD). Protective Gloves:IMPERVIOUS Eye Protection:CHEMICAL SPLASH GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health TO SUPRESS VAPORS USE 100:1(WATER:ETHYLENE OXIDE).CHRONIC HEALTH HAZARDS:SKIN-SENSITIZATION;EYES-CATARACT FORMATION;INHAL-CHROMOSOMAL ABERRATIONS,PERIPHERAL NEUROTOXIC EFFECTS,NUMBING OF THE SENSE OF SMELL;INGEST-ANEMIA,LIVER,ADRENAL AND KIDNEY DAMAGE. ================== Physical/Chemical Properties ================== HCC:G8 Boiling Pt:B.P. Text:51.0F,10.6C Vapor Pres:1094 Vapor Density:1.5 Spec Gravity:0.871 pH:7 Evaporation Rate & Reference:72 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:GAS/LIQUID;COLORLESS;SWEET ETHER-LIKE ODOR(ODOR THRESHOLD=700PPM) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SELF-POLYMERIZING CATALYSTS(EG.K,SNCL(ANH),AL,FE,ALCOHOLS,MERCAPTANS,CU,OXIDES OF ALUMINUM OR IRON). Stability Condition to Avoid:TEMPERTURES ABOVE 85F,SOURCES OF IGNITION.EXPLOSIVELY DECOMPOSES ABOVE 800F. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE Conditions to Avoid Polymerization:SELF-POLYMERIZING CATALYSTS(EG.K,SNCL(ANH),AL,FE,ALCOHOLS,MERCAPTANS,CU,OXIDES OF ALUMINUM OR IRON). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.RCRA CODE IS U115. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.