FISHER SCIENTIFIC -- METHYL SALICYLATE, 03695500 -- -
===================== Product Identification ===================== Product ID:METHYL SALICYLATE, 03695500 MSDS Date:12/12/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL SALICYLATE. LD50:(ORAL,RAT) 887 MG/KG. CAS:119-36-8 RTECS #:VO4725000 > Wt:99. ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS & TOXICOLOGICAL INFO. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE IRRITATION. SKIN: CAUSES MODERATE IRRITATION. MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INGESTION: MAY CAUSE NAUSEA AND VOMITING. MAY BE HARMFUL IF SWALLOWED. SYSTEMIC EFF ECTS OF EXPOSURE INCLUDE INITIAL STIMULATION AND LATER CENTRAL NERVOUS SYSTEM DEPRESSION. SYMPTOMS INCLUDE CONVULSIONS, RESPIRATORY FAILURE, CARDIAC COLLAPSE, AND POSSIBLE DEATH. INHALATION: CAUSES RE SPIRATORY TRACT IRRITATION. IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. MAY CAUSE EFFECTS SIMILAR TO THOSE DESCRIBED FOR INGESTION. MAY CAUSE LUNG DAMAGE. CHRONIC: MAY CAUSE LIVER AND KIDNEY DAMAGE. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. Effects of Overexposure:HLTH HAZ: REPEATED EXPOSURE MAY CAUSE METABOLIC DISTURBANCES. CAUTION! THIS SUBSTANCE HAS CAUSED ADVERSE REPRODUCTIVE AND FETAL EFFECTS IN ANIMALS. TARGET ORGANS: KIDNEYS, HEART, CENTRAL NERVOUS SYSTE M, LIVER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH WITH PLENTY OF WATER FOR AT LST 15 MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: IMMED FLUSH WITH PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING C ONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS OR PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MED AID IMMED. INDUCE VOMIT BY GIVING 1 TSP OF SYRUP OF I PECAC. CALL POIS CTL CTR. INHAL: REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ANTID OTE: NO SPECIFIC ANTIDOTE EXISTS. ===================== Fire Fighting Measures ===================== Flash Point:=96.1C, 205.F Autoignition Temp:=454.4C, 850.F Lower Limits:NOT AVAIL Upper Limits:NOT AVAIL Extinguishing Media:WATER OR FOAM MAY CAUSE FROTHING. USE CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. Unusual Fire/Explosion Hazard:NFPA RATING: HEALTH - 1; FLAMMABILITY - 1; REACTIVITY - 0. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. SWEEP UP, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. REMOVE ALL SOURCES OF IGNITION. AB SORB SPILL USING AN ABSORBENT, NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND OR VERMICULITE. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:GROUND AND BOND CONTAINERS WHEN TRANSFERRING MATERIAL. DO NOT GET ON SKIN OR IN EYES. DO NOT INGEST OR INHALE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health PHYSICAL AND CHEMICAL PROPERTIES: VAP DENS: 5.24 (AIR=1). MOLECULAR FORMULA: C8H8O3. ================== Physical/Chemical Properties ================== Boiling Pt:=223.3C, 433.9F Melt/Freeze Pt:=-8.6C, 16.5F Decomp Temp:Decomp Text:NOT AVAILABLE Vapor Pres:0.1 MM HG @ 20C Vapor Density:SUPP DATA Spec Gravity:1.18 (WATER=1) pH:NOT AVAILABLE Viscosity:NOT AVAILABLE Solubility in Water:SLIGHTLY SOLUBLE Appearance and Odor:COLORLESS TO YELLOW-RED LIQUID; WINTERGREEN ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES. Stability Condition to Avoid:STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS UNDER NORMAL STORAGE AND HANDLING CONDITIONS. AVOID INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SALICYCLIC ACID. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information =================== Toxicological Information:CAS # 119-36-8: RTECS # VO4725000: LD50:(ORAL,MOUSE) 1110 MG/KG; LD50:(ORAL,RABBIT) 1300 MG/KG. EPIDEMIOLOGY: NO INFORMATION AVAILABLE. TERATOGENICITY: EFFECTS ON NEWBORN: LIVER BIRTH INDEX & VIABILIT Y INDEX, ORAL-RAT TDLO=36450 MG/KG. SPECIFIC DEVELOPMENTAL ABNORMALITIES: CENTRAL NERVOUS SYSTEM, CRANIOFACIAL & MUSCULOSKELETAL, SUBCUTANEOUS- RAT TDLO=500 MG/KG. REPRODUCTIVE EFFECTS: NO INFORMATION AVAILABLE. NEUROTOXICITY: NO INFORMATION AVAILABLE. MUTAGENICITY: NO INFORMATION AVAILABLE. OTHER STUDIES: NONE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NO INFORMATION AVAILABLE. ENVIRONMENTAL FATE: NO INFORMATION REPORTED. PHYSICAL/CHEMICAL: NO INFORMATION AVAILABLE. OTHER STUDIES: NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS; F-SERIES; P-SERIES; & U-SER IES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:U.S. DOT: SHIPPING NAME: NO INFORMATION AVAILABLE. IATA: SHIPPING NAME: NO INFORMATION AVAILABLE. RID/ADR: SHIPPING NAME: NO INFORMATION AVAILABLE. IMO: SHIPPING NAME: NO INFORMATION AVAILABLE. CANADA TDG: SHIPPING NAME: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 119-36-8: ACUTE, CHRONIC. SECTION 313: NO CH EMICALS ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:TSCA: CAS # 119-36-8 IS LISTED ON THE TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEM TEST RULES: NONE OF THE CHEMS IN THIS PROD ARE U NDER A CHEM TEST RULE. SECTION 12B: NONEOF THE CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMS IN THIS MATL HAVE A SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL D OES NOT CONTAIN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF THE CHEMS IN THIS PROD ARE LISTED AS(STATE REGULATORY INFO) State Regulatory Information:CAS # 119-36-8 CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: PENNSYLVANIA. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. -- FEDERAL REGULATORY: HAZ SUBSTANCES UNDER THE CWA. NONE OF THE CHEMS IN THIS PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMS IN THIS PROD ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA. OSHA: NONE OF TH E CHEMS IN THIS PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS: EUROPEAN LABELI NG I/A/W EC DIRECTIVES: HAZ SYMBOLS: XN. RISK PHRASES: R 22 - HARMFUL IF SWALLOWED; R 36/38 - IRRITATING TO EYES & SKIN. SAFETY (OTHER INFO) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. 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