VAN WATERS AND ROGERS INC -- CHROMIC ACID -- 6810-00-264-6517
===================== Product Identification ===================== Product ID:CHROMIC ACID MSDS Date:02/01/1993 FSC:6810 NIIN:00-264-6517 === Responsible Party === Company Name:VAN WATERS AND ROGERS INC Address:1600 NORTON BLDG. City:SEATTLE State:WA ZIP:98104-1564 Country:US Info Phone Num:408-435-8700 Emergency Phone Num:408-435-8700/800-424-9300(CHEMTREC) Preparer's Name:C.A.EISENHART CAGE:87664 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:VAN WATERS AND ROGERS INC., UNIVAR CORP. Address:1600 NORTON BLDG. 801 2ND AVENUE Box:City:SEATTLE State:WA ZIP:98104-1564 Country:US Phone:206-447-5911/800-424-9300(CHEMTREC) CAGE:87664 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM (VI) OXIDE CAS:1333-82-0 RTECS #:GB6650000 Fraction by Wt: >99% OSHA PEL:C, 0.1 MG/M3 (CRO3) ACGIH TLV:0.05 MG/M3(CR); 8990 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NIOSH:.025MG(CR4)/M3;10HR TWA=.05MG Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE-EYE:DUST IS EXTREMELY CORROSIVE;CAN CAUSE SEVERE DAMAGE.SKIN:IRRITATION.INHAL:IRRITATION OF THE NASAL SEPTUM & RESPIRATORY TRACT.INGESTION:CAN CAUSE EXTREME TISSUE DESTRUCTION,KIDNEY FAILURE & D EATH.CHRONIC-EYE:CONJUNCTIVITIS.SKIN:ESPEC. BROKEN,MAY CAUSE "CHROME SORE". Explanation of Carcinogenicity:CR (VI) COMPOUNDS ARE CONSIDERED SUSPECT CARCINOGENS. Effects of Overexposure:EYES:CORROSIVE,SEVERE DAMAGE,PERMANENT INJURY,BLINDNESS;SKIN:BURNS,IRRITATION,CHROME SORES,SKIN SENSITIZATION, KIDNEY FAIL SEPTUM & RESPIRATORY TRACT,ASTHMA-LIKE SYMPTOMS;INGESTION: TISSUE DISTRUCTION ,SEVERE INJURY,DELAYED TOXIC EFFECTS,KIDNEY OR LIVER FAILURE. Medical Cond Aggravated by Exposure:CONTACT WITH BROKEN SKIN CAN CAUSE "CHROME SORES".SKIN CAN BECOME SENSITIZED AND MASSIVE OVER-EXPOSURE TO SOLUTIONS CAN ABSORB HARMFUL AMOUNTS, LEADING TO KIDNEY FAILURE AND DEATH. ======================= First Aid Measures ======================= First Aid:EYE:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.GET MEDICAL ATTENTION.SKIN:IMMEDIATELY FLUSH WITH RUNNING WATER FOR 15 MIN.DESTROY CONTAMINATED SHOES.CALL A DOCTOR.INHALATION:REMOVE TO FRESH AIR.G IVE CPR IF NEEDED.CALL A PHYSICIAN.INGESTION:DON'T INDUCE VOMITING.IF CONSCIOUS,GIVE LOTS OF WATER/MILK.GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL OR CO2. DO NOT USE WATER.(UNDER CERTAIN CONDITIONS CONTACT WITH WATER CAN CAUSE STEAM EXPLOSIONS). Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:PRODUCT MAY CAUSE FIRE IF IT DRYS ON CLOTHING,WOOD,COMBUSTIBLES.CONTACT WITH FLAMMABLE MATERIALS MAY CAUSE IMMEDIATE FIRE OR EXPLOSION,ESPECIALLY IF HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RESPIRATOR EQUIPPED WITH PARTICULATE FILTERS AND EYE PROTECTION. SWEEP UP AND DISPOSE OF IN DOT APPROVED WASTE CONTAINERS. Neutralizing Agent:20% SODIUM BICARBONATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED PLACE AWAY FROM OTHER CHEMICALS & SOURCES OF CONTAMINATION.KEEP CONTAINER TIGHTLY CLOSED.DO NOT STORE IN HUMID PLACE Other Precautions:DO NOT CUT,GRIND,WELD OR DRILL NEAR CONTAINER.TREAT EMPTY CONTAINERS AS IF THEY WERE FULL.FOLLOW HAZARD WARNINGS. DO NOT GET IN EYES,SKIN OR CLOTHING.DO NOT BREATHE THE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED CARTRIDGE RESPIRATOR FOR ACID MISTS. Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING DUST EMISSIONS AT THE POINT OF USE BELOW THE PEL. Protective Gloves:PVC GLOVES WITH GAUNTLETS. Eye Protection:CHEMICAL GOGGLES & FULL FACESHIELD. Other Protective Equipment:ACID RESISTANT SLICKER SUIT WITH PVC APRON & BOOTS. EYEWASH STATION & SAFETY SHOWER. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING IMMEDIATELY.DO NOT LAUNDER AT HOME.AVOID WEARING LEATHER SHOES & GLOVES.TAKE SHOWER DAILY. Supplemental Safety and Health NOTE TO PHYSICIAN:MASSIVE OVEREXPOSURE TO SOLUTIONS COULD LEAD TO KIDNEY FAILURE AND DEATH.EARLY RENAL DIALYSIS IS RECOMMENDED.ONE GRAM ASCORBIC ACID (ORAL/IV) FOLLOWED BY 100 MG T.I.D. FOR 14 DAYS.SK IN ULCERS MAY BE TREATED BY REMOVAL FROMEXPOSURE,DAILY CLEANSING & DEBRIDEMENT, & ANTIBIOTIC CREAM. ================== Physical/Chemical Properties ================== HCC:D3 NRC/State Lic Num:NONE Melt/Freeze Pt:M.P/F.P Text:387F (197C) Spec Gravity:2.7 Solubility in Water:62.5% Appearance and Odor:DARK RED FLAKES, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS,COMBUSTIBLE MATERIALS SUCH AS OILS OR GREASES,WATER AND ORGANICS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CHROMIC OXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.