MATHESON TRI-GAS, INC. -- HELIUM -- -
===================== Product Identification ===================== Product ID:HELIUM MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:HELIUM CAS:7440-59-7 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: nausea, vomiting, dizziness, tingling sensation, suffocation, convulsions, coma LONG TERM EXPOSURE: no information on significant adverse effects SKIN CONTACT: SHORT TERM EXPOSURE: no information on significant adverse effects LONG TERM EXPOSURE: no information is available EYE CONTACT: SHORT TERM EXPOSURE: no information on significant adverse effects LONG TERM EXPOSURE: no information is available INGESTION: SHORT TERM EXPOSURE: no information on significant adverse effects LONG TERM EXPOSURE: no information is available Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash exposed skin with soap and water. EYE CONTACT: Flush eyes with plenty of water. INGESTION: If a large amount is swallowed, get medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. ===================== Fire Fighting Measures ===================== Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck, evacuation radius: 800 meters (1/2 mile). Unusual Fire/Explosion Hazard:Negligible fire hazard. Containers may rupture or explode if exposed to heat. ================== Accidental Release Measures ================== Spill Release Procedures:Stop leak if possible without personal risk. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Protective Gloves:Protective gloves are not required. Eye Protection:Eye protection not required, but recommended. Other Protective Equipment:Protective clothing is not required. Supplemental Safety and Health HELIUM: ACGIH (simple asphyxiant) ================== Physical/Chemical Properties ================== Boiling Pt:-452 F (-269 C) Melt/Freeze Pt:-458 F (-272 C) @ 26 atm Vapor Pres:1719 mmHg @ -268 C Vapor Density:0.138 Spec Gravity:Not applicable pH:Not applicable Evaporation Rate & Reference:Not applicable Solubility in Water:0.94% @ 0 C Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:odorless Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Protect from physical damage and heat. Containers may rupture or explode if exposed to heat. Hazardous Decomposition Products:Thermal decomposition products: miscellaneous decomposition products Thermal decomposition products: miscellaneous decomposition products Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:Not available ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Helium, compressed ID NUMBER: UN1046 HAZARD CLASS OR DIVISION: 2.2 LABELING REQUIREMENTS: Nonflammable gas ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No REACTIVE: No SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.