DEGESCH AMERICA INC -- CALCIUM CYANIDE, A-DUST,G-FUMIGANT -- 6840-00F029761
===================== Product Identification ===================== Product ID:CALCIUM CYANIDE, A-DUST,G-FUMIGANT MSDS Date:06/01/1986 FSC:6840 NIIN:00F029761 === Responsible Party === Company Name:DEGESCH AMERICA INC Address:275 TRIANGLE DR Box:116 City:WEYERS CAVE State:VA ZIP:24486 Country:US Info Phone Num:703-234-9281 Emergency Phone Num:703-234-9281 CAGE:59471 === Contractor Identification === Company Name:DEGESCH AMERICA INC Address:275 TRIANGLE DR Box:116 City:WEYERS CAVE State:VA ZIP:24486 Country:US Phone:703-234-9281 CAGE:59471 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CYANIDE CAS:592-01-8 RTECS #:EW0700000 Fraction by Wt: 42% Ingred Name:HYDROGEN CYANIDE (REACTION PRODUCT OF CALCIUM CYANIDE & WATER) CAS:74-90-8 RTECS #:MW6825000 Other REC Limits:10 PPM OSHA PEL:S, 10 PPM STEL ACGIH TLV:S, C 10 PPM; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HYDROGEN CYANIDE IS VERY TOXIC & EXTREMELY FAST ACTING. BREATHING/SWALLOWING SMALL AMOUNT OF CYANIDE MAY BE FATAL. A FEW MINUTES OF EXPOSURE TO 300 PPM MAY RESULT IN DEATH. EXPOSURE TO 150 PPM FOR FRO M 0.5 TO 1 HOUR MAY ENDANGER LIFE. AVERAGE FATAL DOSE OF HYDROGEN CYANIDE IS 50-60MG. MAY BE ABSORBED. Explanation of Carcinogenicity:NONE Effects of Overexposure:EXPOSURE TO HYDROCYANIC ACID MAY CAUSE WEAKNESS, HEADACHE, CONFUSION, NAUSEA, VOMITING, INCREASED RATE OF RESPIRATION OR SLOW/GASPING RESPIRATION, EYE & SKIN IRRITATION. THIS IS FOLLOWED BY COLLAPSE, COMA, CONVULSIONS, & DEATH. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION. AVOID MOUTH-TO-MOUTH RESUSCITATION IF POSSIBLE. USE CYANIDE ANTIDOTE KIT. KEEP QUIET & MAINTAIN NORMAL BODY TEMPERATURE. EFFECTS MAY BE DELAYED; KEEP VICTIM UNDER OBSERVATION. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICALS/SAND/EARTH. DON'T USE WATER/CO2. LET FIRE BURN ITSELF OUT. STAY UPWIND/OUT OF LOW AREAS. ISOLATE 200 YARDS Fire Fighting Procedures:MOVE INTACT CALCIUM CYANIDE CASE AWAY FROM FIRE SAFELY. ISOLATE AREA UNTIL GAS DISPERSED. WEAR POSITIVE PRESSURE SCBA W/SPECIAL CHEMICAL-PROOF SUITS. Unusual Fire/Explosion Hazard:EXPLOSION HAZARD OF HYDROGEN CYANIDE IS SEVERE WHEN EXPOSED TO HEAT. CALCIUM CYANIDE WILL REACT W/WATER TO FORM EXPLOSIVE MIXTURES W/AIR. ================== Accidental Release Measures ================== Spill Release Procedures:DOWNWIND UP TO 0.5 MILES/WIDTH OF 0.25 MILES. TAKE HYDROGEN CYANIDE GAS CONCENTRATION READING W/DETECTOR TUBE. STAY UPWIND/WEAR SCBA. DON'T USE WATER FOR 24 HRS. OVERPACK DAMAGED CONTAINER/SHOVEL/PLAC E IN GAS-TIGHT CONTAINER. REMOVE IGNITION SOURCES. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN LOCKED/DRY/WELL-VENTILATED AREA AWAY FROM HEAT. POST AS PESTICIDE STORAGE AREA. DON'T STORE IN BUILDINGS INHABITED BY HUMANS/DOMESTIC ANIMAL. Other Precautions:DON'T ALLOW WATER/OTHER LIQUIDS TO CONTACT PRODUCT. SEE EPA APPROVED LABELING FOR ADDITIONAL PRECAUTIONS/DIRECTIONS FOR USE. FOR RETAIL SALE & USE ONLY BY CERTIFIED APPLICATORS/PERSONS UNDER DIRECT SU PERVISION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED SCBA OR COMBINATION AIR-SUPPLIED/SCBA RESPIRATOR FOR ENTRY INTO AFFECTED AREAS TO CORRECT PROBLEMS. Ventilation:LOCAL: ADEQUATE TO REDUCE HYDROGEN CYANIDE LEVELS TO BELOW TLV. Protective Gloves:RUBBER Eye Protection:GLASSES/GOGGLES Other Protective Equipment:FULL-FACE RESPIRATORY PROTECTION, PROTECTIVE CLOTHING Supplemental Safety and Health NOTE TO PHYSICIAN: CYANIDE CAN BE RAPIDLY LETHAL BY BLOCKING OXYGEN UTILIZATION AT THE CELLULAR LEVEL, FORMING CYANMETHEMOGLOBIN FROM METHEMOGLOBIN. GIVE SODIUM NITRATE AS ANTIDOTE INTRAVENOUSLY FOLLO WED BY SODIUM THIOSULFATE. INHALE AMYL NITRITE PEARLS. OXYGEN/ARTIFICIAL RESPIRATION ARE SUPPORTIVE MEASURES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 350 C Melt/Freeze Pt:M.P/F.P Text: 350 C Vapor Pres:LOW Solubility in Water:SOLUBLE, REACTS Appearance and Odor:TAN POWDERED MATERIAL W/FAINT ODOR OF BITTER ALMONDS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS/WATER/CO2/STEAM/ACIDS/ACID FUMES/ACETALDEHYDE/ALKALINE MATERIALS Stability Condition to Avoid:EXTREME HEAT, FLAME, FLARES, & OTHER SOURCES OF IGNITION Hazardous Decomposition Products:HIGHLY TOXIC FUMES, HYDROGEN CYANIDE (HYDROCYANIC ACID/PRUSSIC ACID). Conditions to Avoid Polymerization:HYDROGEN CYANIDE IN CYLINDERS MAY POLYMERIZE SPONTANEOUSLY W/EXPLOSIVE VIOLENCE; WILL NOT OCCUR W/CALCIUM CYANIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.