MALLINCKRODT INC -- COBALT SULFATE -- 6810-00N062410
===================== Product Identification ===================== Product ID:COBALT SULFATE MSDS Date:08/13/1985 FSC:6810 NIIN:00N062410 === Responsible Party === Company Name:MALLINCKRODT INC Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT (II) SULFATE (1:1); (COBALT SULFATE-TSCA CAS #, ANHYDROUS) CAS:10124-43-3 RTECS #:GG3100000 OSHA PEL:0.05 MG C0/M3 ACGIH TLV:0.05 MG C0/M3 Ingred Name:COBALT (II) SULFATE (1:), HEPTAHYDRATE; (FORMULA COSO*47H*2O CAS #, HYDRATED) CAS:10026-24-1 RTECS #:GG3200000 OSHA PEL:100 UG/CUM (CO) ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 768 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT, SYMPTOMS MAY INCLUDE COUGHING, SHORTNESS OF BREATH, AND NAUSEA. INHALATION OF COBALT DUST AND FUMES IS ASSOCIATED WITH AN INCREASED IN CIDENCE OF LUNG DISEASE. INGESTION: MAYCAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, VASODILATION, MILD (EFTS OF OVEREXP) Explanation of Carcinogenicity:COBALT (II) SULFATE (1:1): IARC MONO ON EVALUATION OF CARCIN RISK OF CHEM TO MAN, VOL 52, PG 363, 1991: GROUP 2B. Effects of Overexposure:HLTH HAZ: HYPOTENSION, RASH, AND RINGING IN THE EARS. SKIN: MAY CAUSE IRRITATION, REDNESS, PAIN. EYES: MAY CAUSE IRRITATION, REDNESS, PAIN. CHRONIC: REPEATED ORAL ADMINISTATION MAY PRODUCE A GOITER AN D REDUCED THYROID ACTIVITY. PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE DERMATITIS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANY THING BY MOUTH TO UNCON PERS. CALL MD IMMED. SKIN: REMOVE ANY CONTAM CLTHG. WIPE OFF EXCESS FROM SKIN. WASH SKIN W/SOAP & WATER FOR AT LEAST 15 MIN. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. (SUP DAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL MAY REQUIRE RESPIRATORY PROTECTION FROM DUST. SPILLS: SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED T O AVOID DUST DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, A NIOSH/MSHA APPRVD DUST/MIST RESP W/CHEM GOGG MAY BE WORN, IN GEN, UP TO 10 TIMES TLV. CONSULT RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A NIOSH/MSHA APPRVD SUPP-AIR FULL FACE PIECE RESP/AIRLINED HOOD MAY BE WORN. Ventilation:SYS OF LOC &/GEN EXHAUST REC TO KEEP EMPLOYEE EXPOS < AIRBORNE EXPOS LIM. LOC EXHAUST VENT IS GEN PREFERRED (SUP DAT) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS . Other Protective Equipment:WEAR CLEAN BODY-COVERING CLOTHING. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. Supplemental Safety and Health FIRST AID PROC: EYES: WASH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN. IF IRRIT DEVELOPS, GET MED ATTN. VENT: BECAUSE IT CAN CTL EMISSIONS OF CONTAM AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENT, A MANUAL OF REC PRACT", MOST RECENT EDITION, FOR DETAILS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1355F,735C Melt/Freeze Pt:M.P/F.P Text:207F,97C Spec Gravity:2.03 Solubility in Water:60.4G/100G WATER Appearance and Odor:LARGE IRREGULAR DARK RED TRANSPARENT CRYSTALS, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INCOMPATIBILITY DATA FOUND. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE WITH LCOAL, SATE, AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.