FISHER SCIENTIFIC -- SODIUM BOROHYDRIDE, S678 10, S678 25, S678-10 -- -
===================== Product Identification ===================== Product ID:SODIUM BOROHYDRIDE, S678 10, S678 25, S678-10 MSDS Date:12/12/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100/703-527-3887 Resp. Party Other MSDS Num.:REVISION 5. Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BOROHYDRIDE. (MOLECULAR FORMULA: H4BNA). (EINECS # 241-004-4). CAS:16940-66-2 RTECS #:ED3325000 > Wt:98. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: DANGER! FLAMMABLE SOLID. CORROSIVE. MOISTURE SENSITIVE. MAY CAUSE LUNG DAMAGE, SEVERE RESPIRATORY AND DIGESTIVE TRACT IRRITATION WITH POSSIBLE BURNS. MAY CAUSE SEVERE EYE AND SKIN IRRITATION WITH POSSIBLE BURNS. CONTACTWITH WATER OR STEAM MAY CAUSE FIRE OR EXPLOSION HAZARD. LIBERATES FLAMMABLE HYDROGEN GAS. TARGET ORGANS: NONE. ACUTE: EYES: MAY CAUSE IRREVERSIBLE EYE INJURY. CO NTACT WITH EYES MAY CAUSE SEVERE IRRITATION, AND POSSIBLE BURNS. SKIN: MAY BE ABSORBED THROUGH SKIN. MAY CAUSE SEVERE SKIN IRRITATION WITH POSSIBLE BURNS, ESPECIALLY IF SKIN IS WET OR MOIST. INGESTIO N: MAY CAUSE SEVERE (OVEREXPOSURE) Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. Effects of Overexposure:HEALTH HAZARDS (ACUTE): GASTROINTESTINAL TRACT IRRITATION WITH NAUSEA, VOMITING, AND POSSIBLE BURNS. INHALATION: IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. CAUSES SEVERE IRRITATI ON OF UPPER RESPIRATORY TRACT WITH COUGHING, BURNS, BREATHING DIFFICULTY, AND POSSIBLE COMA. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DEFATTING AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKIN WITH PLE NTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID IMMEDIATEL Y. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. NOTE TO PHYSICIAN: TRE AT SYMPTOMATICALLY AND SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE. Autoignition Temp:=250.C, 482.F Lower Limits:NOT AVAIL. Upper Limits:NOT AVAIL. Extinguishing Media:USE APPROVED CLASS D EXTINGUISHING AGENTS OR SMOTHER WITH DRY SAND, CLAY, OR SODIUM BICARBONATE. DO NOT USE WATER DIRECTLY ON FIRE. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:AS IN ANY FIRE, WEAR NISOH-APPROVED SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:DUSTS AT SUFFICIENT CONCENTRATIONS CAN FORM EXPLOSIVE MIXTURES WITH AIR. COMBUSTION GENERATES TOXIC FUMES. WATER REACTIVE. MATERIAL WILL REACT WITH WATER AND MAY RELEASE A FLAMMABLE AND/OR TOXIC GAS. CONTACT WITH WATER AND STEAM MAY CAUSE A FIRE OR EXPLOSION HAZARD. LIBERATES FLAMMABLE HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP, THEN PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. AVOID GENERATING DUSTY CONDITIONS. ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLING: USE WITH ADEQUATE VENTILATION. MINIMIZE DUST GENERATION AND ACCUMULATION. KEEP CONTAINER TIGHTLY CLOSED. DO NOT GET ON SKIN OR IN EYES. DO NOT INGEST OR INHALE. DO NOT ALLOW CONTACT WITH WAT ER. STORAGE: KEEP FROM CONTACT WITH OXIDIZING MATERIALS. STORE IN A COOL, DRY, (OTHER PRECAUTIONS) Other Precautions:HANDLING AND STORAGE (CONT): WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM WATER. WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE PROP ER PERSONAL PROTECTIVE EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Protective Gloves:IMPERVIOUS GLOVES . WEAR APPROP PROTECTIVE GLOVES TO PREVENT SKIN EXPOS. Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL FACESHIELD . (SUPP DATA) Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE (MFR). Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health DANGER! FLAMMABLE SOLID. CORROSIVE. MOISTURE SENSITIVE. NO OSHA VACATED PELS ARE LISTED FOR THIS CHEMICAL. EYE PROTECTION: WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES AS DESCRIBE D BY OSHA'S EYE AND FACE PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD EN166 (MFR). ================== Physical/Chemical Properties ================== Boiling Pt:=400.C, 752.F Melt/Freeze Pt:=36.1C, 97.F M.P/F.P Text:DECOMPOSES. Decomp Temp:=400.C, 752.F Vapor Pres:NEGLIGIBLE. Vapor Density:NOT AVAIL. Spec Gravity:1.074 pH:ALKALINE IN SOL Viscosity:NOT AVAILABLE. Evaporation Rate & Reference:NEGLIGIBLE. Solubility in Water:SOLUBLE & REACTIVE. Appearance and Odor:WHITE SOLID. ODOR: NONE REPORTED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ALCOHOLS, COMBUSTIBLE MATERIALS , METAL SALTS, STRONG OXIDIZERS. LIBERATES HYDROGEN UPON CONTACT WITH WATER. Stability Condition to Avoid:STABLE. HOWEVER, MAY DECOMPOSE IF HEATED. MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR WATER. AVOID INCOMPATIBLE MATERIALS, MOISTURE, CONTACT WITH WATER, TEMPERATURES ABOVE 200C. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF BORON, BORANE, HYDROGEN GAS. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information =================== Toxicological Information:L50/LC/50: NOT AVAILABLE. NO INFORMATION AVAILABLE FOR EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFFECTS, OR NEUROTOXICITY. MUTAGENICITY: REFER TO RTECS ED3325000 FOR SPECIFIC INFORMATION. OTHER STUD IES: NONE. ===================== Ecological Information ===================== Ecological:NO INFORMATION AVAILABLE FOR ECOTOXICITY, ENVIRONMENTAL FATE, OR PHYSICAL/CHEMICAL. OTHER: NOT AVAIL. EUROPEAN LABELING IN ACCORDANCE W/EC DIRECTIVES: HAZARD SYMBOLS=XN F. RISK PHRASES: R 15 CONTA CT W/WATER LIBERATES HIGHLY FLAMMABLE GASSES. R22 HARMFUL IF SWALLOWED. R 36/37/38: IRRITATING TO EYES, RESPIRATORY SYSTEM & SKIN. SAFETY PHRASES: S 18 HANDLE & OPEN CONTAINER W/CARE. S 22: DO NOT IN HALE DUST. WGK (WATER DANGER/PROTECTION): CAS# 16940-66-2. CANADA: CAS# 16940-66-2 IL LISTED ON CANADA'S DSL/NDSL LIST. PRODUCT HAS A WHMIS CLASSIFICATION OF B4, D2B. CAS# 16940-66-2 IS NOT LISTED ON CANADA'S INGREDIENT DISCLOSURE LIST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATIONS OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE L ISTED. RCRA-F SERIES, RCRA P-SERIES, AND RCRA U-SERIES: NONE LISTED. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. =================== MSDS Transport Information =================== Transport Information:US DOT. SHIPPING NAME: SODIUM BOROHYDRIDE. HAZARD CLASS: 4.3. UN NUMBER: UN1426. PACKING GROUP: I. NO INFORMATION AVAILABLE FOR IMO, IATA, OR RID/ADR. CANADIAN TDO: SHIPPING CLASS: SODIUM BOROHYDRIDE. HAZARD CLASS: 4.3. UN NUMBER: UN1426. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTION 302: NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ OR TPQ. SARA CODES: CAS# 16940-66-2: ACUTE, FLAMMABLE, REACTIVE. NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. FEDERAL REGULATIONS (CONT): POLLUTANTS UNDER THE CLEAN WATER ACT. NO CHEMICALS IN THIS PRODUCT CONSIDERED HIGHLY HAZARDOUS BY OSHA. HAZARD SYMBOLS: XN F. RISK PHRASES: 15 22 36/37/38. Federal Regulatory Information:CAS# 16940-66-2 IS LISTED ON TSCA INVENTORY. NONE OF THE CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE. NONE OF THE CHEMICAL S ARE LISTED UNDER TSCA SECTION 12B. NONE OF THE CHEMICALS IN THE MATERIAL HAVE A SIGNIFICANT NEW USE RULE (SNUR) UNDER TSCA. THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS 1 OZONE DEPLETORS, OR CLASS 2 OZONE DEPLETORS UNDER THE CLEAN AIR ACT. NONE OF THE CHEMICALS IN THIS PRODU CT ARE LISTED AS HAZARDOUS SUBSTANCES UNDER THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS PRIORITY POLLUTANTS OR TOXIC (SARA) State Regulatory Information:SODIUM BOROHYDRIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: NEW JERSEY. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.