E I DUPONT DE NEMOURS & CO -- ACETAL RESIN, 500AF NC010 -- 6810-00N020609
===================== Product Identification ===================== Product ID:ACETAL RESIN, 500AF NC010 MSDS Date:12/21/1988 FSC:6810 NIIN:00N020609 === Responsible Party === Company Name:E I DUPONT DE NEMOURS & CO Address:1007 MARKET ST City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-7515 Emergency Phone Num:800-441-3637,800-424-9300(CHEMTREC) CAGE:0ERJ7 === Contractor Identification === Company Name:E I DUPONT DE NEMOURS & CO, INC. Address:1007 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515 CAGE:0ERJ7 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE (SARA III) CAS:50-00-0 RTECS #:LP8925000 OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM; A2; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:FORMALDEHYDE HOMOPOLYMER; (POLYACETAL) Ingred Name:ETHYLENE, TETRAFLUORO-, POLYMER; (POLYTETRAFLUOROETHYLENE) CAS:116-14-3 RTECS #:KX4025000 Ingred Name:STABILIZERS Ingred Name:ANTIOXIDANTS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: INGEST: NOT A PROBABLE ROUTE OF EXPOSURE. SKIN: NOT TOXIC. HOT POLYMER WILL CAUSE THERMAL BURNS. EYE: MECHANICAL IRRITATION. INHAL: FORMALDEHYDE IS HIGHLY IRRITATING TO THE EYES AND UPPER RESPI RATORY TRACT. WHEN THE POLYMER IS THERMALLY DECOMPOSED IT MAY CAUSE POLYMER FUME FEVER. CHRONIC: (SEE EFTS OF OVEREXPOS) Explanation of Carcinogenicity:FORMALDEHYDE: CLASS 2 (NTP); CLASS 2A (IARC)-(LESS THAN 0.1%). OSHA REGULATED CARCINOGEN. Effects of Overexposure:FORMALDEHYDE RELEASED IN SMALL QUANTITY DURING MELT PROCESSING IS CLASSIFIED AS AN ANIMAL CARCINOGEN. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE TO FORMALDEHYDE. ======================= First Aid Measures ======================= First Aid:INHL: IF EXPOSED TO FUMES FROM OVERHEATING OR COMBUSTION, MOVE TO FRESH AIR. CONSULT MD IF SYMPTOMS PERSIST. EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONSULT MD IF SYMPTOMS PERSIST. S KIN: IF MOLTEN POLYMER CONTACTS SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MEDICAL ATTENTION FOR THERMAL BURN. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:322F,161C Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . PROTECTION FROM FUMES OF FORMALDEHYDE AND HYDROGEN FLUORIDE. Unusual Fire/Explosion Hazard:BURNS WITH A COLORLESS FLAME. DUST CLOUD IGNITION TEMPERATURE 440C. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP TO PREVENT A SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DRY STORAGE. KEEP CONTAINERS CLOSED TO PREVENT CONTAMINATION. OPEN CONTAINERS ONLY IN WELL-VENTILATED AREAS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF LOCAL EXHAUST DOES NOT KEEP FORMALDEHYDE CONCENTRATION BELOW 1 PPM, USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST AT PROCESSING EQUIPMENT. Protective Gloves:PROTECTIVE GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:LONG SLEEVE COTTON SHIRT AND LONG PANTS IF HANDLING MOLTEN POLYMER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MATLS TO AVOID: CONTAMINATING TOBACCO PRODUCTS. ================== Physical/Chemical Properties ================== HCC:T7 Melt/Freeze Pt:M.P/F.P Text:342F,172C Spec Gravity:1.54 Solubility in Water:INSOLUBLE Appearance and Odor:GRANULES; SLIGHT FORMALDEHYDE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS & BASES (DECOMP FORMING FORMALDEHYDE). STONG OXIDIZING AGNETS. CARE SHOULD BE TAKEN TO AVOID (SUPP DATA) Stability Condition to Avoid:HEATING ABOVE 230C. Hazardous Decomposition Products:AT TEMPS >230C, FORMS FORMALDEHYDE & CAN ALSO EVOLVE HYDROGEN FLUORIDE & TOXIC FLUORINATED HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION OR LANDFILL IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ALKALINE SCRUBBING TO REMOVE GASEOUS COMBUSTION PRODUCT REQUIRED FOR INCINERATION. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.