ALDRICH CHEMICAL CO -- BORON TRICHLORIDE, 1.0M (SEE SUPP DATA) -- 6810-00N014372
===================== Product Identification ===================== Product ID:BORON TRICHLORIDE, 1.0M (SEE SUPP DATA) MSDS Date:04/11/1988 FSC:6810 NIIN:00N014372 === Responsible Party === Company Name:ALDRICH CHEMICAL CO Box:355 City:MILWAUKEE State:WI ZIP:53201 Country:US Info Phone Num:414-273-3850 CAGE:60928 === Contractor Identification === Company Name:ALDRICH CHEMICAL CO INC Address:1001 WEST ST PAUL AVE Box:355 City:MILWAUKEE State:WI ZIP:53233 Country:US Phone:414-273-3850 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:BORON TRICHLORIDE (SARA III) CAS:10294-34-5 RTECS #:ED1925000 Ingred Name:METHYLENE CHLORIDE (SARA III) CAS:75-09-2 RTECS #:PA8050000 OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA: (E.G. EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR (ING 04) RTECS #:9999999ZZ Ingred Name:ING 03: CHRONICALLY EXPOSED TO CHLOROCARBONS OR CFCS . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THRU SKIN. MATL IS EXTREMELY DESTRUCT TO TISS OF THE MUC MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS A RSLT OF SPASM, INFLAMM & EDEMA OF THE LARYNX & BRONCHI, CHEM PNEUMIT &PULM EDEMA. CHRONIC: POSS CARC. CHLOROCARBON/CHLOROFLUOROCARBON (SEE SUPP DATA) Explanation of Carcinogenicity:DICHLOROMETHANE: IARC 2B, NTP GROUP 2. Effects of Overexposure:MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. MAY CAUSE NERVOUS SYSTEM DISTURBANCES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMED FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS. INH AL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES. INGEST: CALL MD IMMED . ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. DO NOT USE WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:WATER HYDROLYZES MATL LIBERATING ACIDIC GAS WHICH IN CNTCT W/METAL SURFACES CAN GENERATE FLAMM AND/OR EXPLO HYDROGEN GAS. EMITS TOXIC FUMES (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MA TERIAL PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:POSSIBLE CARCINOGEN. NEURO HAZ. DO NOT BREATHE VAPOR. KEEP TIGHTLY CLOSED. DO NOT ALLOW CONTACT WITH WATER. STORE UNDER NITROGEN. REFRIGERATE. Other Precautions:CORR. TOXIC. DO NOT GET IN EYES, ON SKIN/CLTHG. AVOID PRLNG/RPTD EXPOS. NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENL VICIN OF ARC WELDING, OPEN FLAMES OR HOT SURFS. HEAT AND/OR UV RADIA MAY CAUSE THE FORM OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL-RESISTANT GLOVES Eye Protection:CHEM WORK GOGGLES/FACESHLD OPTNL Other Protective Equipment:RUBBER BOOTS AND OTHER PROTECTIVE CLOTHING, SAFETY SHOWER AND EYE BATH. FACESHIELD (8" MINIMUM). Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES . Supplemental Safety and Health MFR'S TRADE NAME/PART NO: SOLN IN DICHLOROMETHANE, 17893-4. EXPLO HAZ: UNDER FIRE CNDTNS. THERMAL DECOMP PRODS MAY INCLUDE HCL & PHOSGENE . HLTH HAZ: (CFC) MATLS HAVE PRODUCED SENSITIZATION OF T HE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (SEE INGRED 03) ================== Physical/Chemical Properties ================== HCC:G6 Vapor Pres:1128 @ 20C Spec Gravity:1.460 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES, ALCOHOLS, REACTS VIOLENTLY WITH WATER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CO, CO*2, HCL GAS, BORON OXIDES. PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSE I/A/W FEDERAL, STATE AND LOCAL LAWS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.