MALLINCKRODT, INC., SCIENCE PRODUCTS DIVISION -- STANNIC CHLORIDE -- -
===================== Product Identification ===================== Product ID:STANNIC CHLORIDE MSDS Date:10/16/1985 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT, INC., SCIENCE PRODUCTS DIVISION Box:M City:PARIS State:KY ZIP:43061 Country:US Info Phone Num:314- 982-5000 Emergency Phone Num:(314) 982-5000 Resp. Party Other MSDS Num.:EFFECTIVE DATE: 10-16-85 SUPERS 07-19-85 CAGE:TO713 === Contractor Identification === Company Name:MALLINCKRODT, INC., SCIENCE PRODUCTS DIVISION Box:M City:PARIS State:KY ZIP:43061 Country:US Phone:314-982-5000 CAGE:TO713 ============= Composition/Information on Ingredients ============= Ingred Name:STANNIC CHLORIDE (HYDRATED) CAS:10026-06-9 OSHA PEL:2 MG(SN)/M3 (TWA) ACGIH TLV:2MG(SN)/M3(TWA) ACGIH STEL:4MG(SN)/M3 Ingred Name:STANNIC CHLORIDE (ANHYDROUS) CAS:7646-78-8 RTECS #:XB8750000 OSHA PEL:2MG(SN)/M3(TWA) ACGIH TLV:2MG(SN)/M3(TWA) ACGIH STEL:4MG(SN)/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION TO THE MUCOUS MEMBRANES. SYMPTOMS MAY INCLUDE COUGHING, SORE THROAT, AND SHORTNESS OF BREATH. INGESTION: MAY CAUSE BURNING PAIN IN MOUTH, NAUSEA, VOMITING & DIARRHEA. MAY CAUSE IRRITATION & BLISTERING TO MUCOUS MEMBRANES. SKIN CONTACT:MAY CAUSE REDNESS, PAIN, & BLISTERNG. EYE CONTACT: IRRITATION, REDNESS, PAIN, BLURRED VISION & DAMAGE. CHRONIC: PROLONGED INHALATION OF DUST OR FUME MAY RESULT IN BENIGN PNEUMOCONIOSIS PRODUCING DISTINCTIVE CHANGES IN LUNGS WITH NO APPARENT DISABILITY OR COMPLICATIONS. Effects of Overexposure:REFER TO HEALTH HAZARD ACUTE AND CHRONIC. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN IMMEDIATELY. SKIN EXPOSURE: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES . CALL A PHYSICIAN. EYE EXPOSURE: WASH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT CONSIDERED TO BE A FIRE HAZARD. USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING & NIOSH APPROVED RESPIRATORY PROTECTION FROM DUST. SPILLS: PICK UP & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR D ISPOSAL IN A METHOD THAT DOES NOT GENERATE DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER HANDLING. PROTECT AGAINST PHYSICAL DAMAGE. STORAGE: KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. Other Precautions:WARNING! HARMFUL IF SWALLOWED. CAUSES IRRITATION. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLIN G. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A DUST/MIST NIOSH APPROVED RESPIRATOR WITH CHEMICAL GOGGLES MAY BE WORN, IN GENERAL, UP TO TEN TIMES THE TLV. CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A NIOS H APPROVED SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS (ECOLOGICAL INFO). Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEMICAL SAFETY GOGGLES &/OR FULL FACE SHIELD WHERE DUSTING OR (SUPP DAT). Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EYE PROTECTION: SPLASHING OF SOLUTIONS IS POSSIBLE. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL. MAINTAIN EYEWASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NO INFO FOUND Melt/Freeze Pt:=56.C, 132.8F M.P/F.P Text:MELTING POINT Vapor Pres:NO INFO FOUND Vapor Density:NO INFO Spec Gravity:NO INFO FOUND Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:SOLUBLE IN WATER Appearance and Odor:WHITE OR SLIGHTLY YELLOW CRYSTALS. SLIGHT ODOR OF HYDROCHLORIC ACID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POTASSIUM, SODIUM, AND TURPENTINE. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:EMITS TOXIC FUMES OF CHLORINE WHEN HEATED TO DECOMPOSITION. =================== Toxicological Information =================== Toxicological Information:(RTECS, 1982): NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE. ===================== Ecological Information ===================== Ecological:N/P. VENTILATION REQUIREMENTS: LOCAL EXHAUST VENTILATION IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF THE CONTAMINANT AT ITS SOURCE PREVENTING DISPERSION OF IT INTO THE GENERAL WO RK AREA. PLEASE REFER TO THE ACGIH DOCUMENT, "INDUSTRIAL VENTILATION, A MANUAL OF RECOMMEDED PRACTICES", MOST RECENT EDITION, FOR DETAILS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN A RCRA APPROVED HAZARDOUS WASTE FACILITY. ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:D. O. T. HAZARD CLASS: NOT REGULATED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.