FISHER SCIENTIFIC, CHEMICAL DIV -- VANADIUM PENTOXIDE -- 6810-00-241-1178 ===================== Product Identification =====================
Product ID:VANADIUM PENTOXIDE
MSDS Date:10/14/1986
FSC:6810
NIIN:00-241-1178
MSDS Number: BDMKZ
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC, CHEMICAL DIV
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:SAME
Emergency Phone Num:201-796-7100
CAGE:1B464
=== Contractor Identification ===
Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:VANADIUM PENTOXIDE (SARA III)
CAS:1314-62-1
RTECS #:YW2460000
Fraction by Wt: 100%.
OSHA PEL:C,0.5 MG/M3
ACGIH TLV:0.05 MG/M3RDUST;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:10-12 MG/KG ORAL-RAT LD50.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SEVERE PULMONARY IRRITANT.PRIMARY SKIN
IRRITANT & SENSITIZER. TOXIC TO BLOOD,LIVER,KIDNEY. SYMPTOMS MAY BE
DELAYED 1-7 DAYS AFTER EXPOSURE.
Effects of
Overexposure:EYE:IRRITATION,CONJUNCTIVITIS.SKIN:IRRITATION,DERMATIT
IS,ECZEMA,SENSITIZATION. INHALE:RHINITIS,NOSEBLEED,DYSPNEA,COUGH,
PULMONARY EDEMA;LIVER,KIDNEY DAMAGE. INGESTION:METALLIC
TASTE,NAUSEA,VOMITING,AB DOMINAL SPASMS, UNCONSCIOUSNESS,DEATH.
Medical Cond Aggravated by Exposure:ANY PREEXISTING CHRONIC
DYSFUNCTION, ALLERGY OR SENSITIVITY.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH 15 MINUTE W/AMPLE WATER. SKIN:REMOVE ALL
CONTAMINATED CLOTHING. WASH THOROUGHLY WITH SOAP AND WATER UNTIL
CLEAN. INHALATION:REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL
RESPIRATION AS REQU IRED. INGESTION:IF CONSCIOUS GIVE 2-4 GLASSES
WATER AND INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. CALL
PHYSICIAN IMMEDIATELY ALL EXPOSURES. TRY TO DETERMINE DOSAGE
RECEIVED.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, FOAM.
Fire Fighting Procedures:USE SCBA PP MODE. REMOVE EXPOSED CONTAINERS OR
COOL W/WATER SPRAY. DO NOT SCATTER SPILLED MATERIAL. DIKE FIREWATER
FOR LATER DISPOSAL IAW ALL LAWS & REGS.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE/EXPLOSION HAZARD FROM
HEAT OR FLAME. DUST, MIST, FUMES ARE HIGHLY TOXIC!
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR ALL PRESCRIBED PROTECTIVE GEAR. REMOVE
INCOMPATIBLE MATERIALS AND AVOID ALL CONTACT. EVACUATE SPILL AREA
AND ESTABLISH VENTILATION. COLLECT SPILL W/ABSORBENT OR SHOVEL.
CAREFULLY PLACE IN CLOSABL E CONTAINER.MARK "POISON". WIPE UP
RESIDUE.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLE AS POISON B MATERIAL!!
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SCBA W/FULL FACEPIECE, PP MODE; OR HIEF FULL
FACEPIECE RESP WITH HI-EFF DUST FILTER; OR SAFHIE SUPPLIED AIR RESP
W/FULL FACEPIECE AND HI-EFF PARTICULATE FILTER.
Ventilation:LOCAL EXHAUST.
Protective Gloves:NEOPRENE NITRILES, PVC
Eye Protection:DUST RESTANT SAFETY GOGGLES.NO CONTACTS!
Other Protective Equipment:EYEWASH FOUNTAIN
Work Hygienic Practices:WASH THOROUGHLY AFTER USE. LAUNDER WORK CLOTHES
AFTER USE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:B.P. Text:3182F/1750C
Spec Gravity:3.4
Solubility in Water:SLIGHT
Appearance and Odor:ODORLESS RED-YELLOW POWDER.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZABLE AND COMBUSTIBLE MATERIALS FORMS EXPLOSIVE PRODUCTS WITH, CA,
S,WATER IGNITION W/CLF*2,EXOTHEM REACT W/LITHIUM
Stability Condition to Avoid:TEMPERATURES ABOVE 700C-LOSES
OXYGEN,W/TOXIC VANADIUM TRIOXIDE RESIDUE.
Hazardous Decomposition Products:OXYGEN, DUSTS, FUMES, MISTS OF
VANADIUM OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT FLUSH TO SEWERS OR WATEWAYS. RECLAIM OR
LANDFILL IAW ALL LAWS & REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.