ASHLAND OIL INC -- ISOPROPANOL 91% -- 6810-00N056907
===================== Product Identification ===================== Product ID:ISOPROPANOL 91% MSDS Date:01/20/1993 FSC:6810 NIIN:00N056907 === Responsible Party === Company Name:ASHLAND OIL INC Box:2219 City:COLUMBUS State:OH ZIP:43216 Country:US Info Phone Num:614-889-3333 Emergency Phone Num:800-274-5263 CAGE:60016 === Contractor Identification === Company Name:ASHLAND CHEMICAL CO Box:2219 City:COLUMBUS State:OH ZIP:43216-2219 Country:US Phone:614-790-3333/800-274-5263 CAGE:34897 Company Name:ASHLAND OIL INC ASHLAND CHEMICAL CO DIV Address:831 5TH AVE S Box:2219 City:KENT State:WA ZIP:98031 Country:US CAGE:60016 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 91% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 500 STEL Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FIRST AID PROC: ANYTHING BY MOUTH TO UNCON PERSON. GET MED ATTN IMMED. INHAL: IF AFFECTED, REMOVE TO FRESH AIR. (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: IF BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HAS STOPPED GIVE ARTF RESP. KEEP PERSON WARM, QUIET & GET MED ATTN. RTECS #:9999999ZZ Ingred Name:SPILL PROC: SPKS). PERSONS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: COMPLETED. STOP SPILL AT SOURCE. PVNT FROM ENTERING DRAINS, SEWERS, STREAMS/OTHER BODIES OF WATER. PVNT (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH AS REQD. PUMP/VACUUM TRANSFER SPILLED PROD TO CLEAN CNTNRS FOR (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: RECOVERY. ABSORB UNRECOVERABLE PROD. TRANSFER CONTAMD ABSORB, SOIL & OTHER MATLS TO CNTNRS FOR DISPOSAL. RTECS #:9999999ZZ Ingred Name:OTHER PREC: "IGNITION" TEMP VALUES CANNOT BE TREATED AS SAFE OPERATING TEMPS IN CHEM PROCESSES W/OUT ANALYSIS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: OF ACTUAL PROCESS CNDTNS. ANY USE OF THIS PROD IN ELEVATED TEMP PROCESSES SHOULD BE THORO EVALUATED TO (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: ESTABLISH & MAINTAIN SAFE OPERATING CONDITIONS. RTECS #:9999999ZZ Ingred Name:RESP PROT: CNDTNS (SEE SFTY EQUIP SUPPLIER). ENGINEERING/ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: EXPOS TO LIQ/VAP MAY CAUSE IRRIT. SYMPS MAY INCL BURNING, TEARING, REDNESS & SWELL. SKIN: EXPOS MAY CAUSE MILD IRRIT. PRLNG/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS, BURNING, DRYIN G & CRACKING & SKIN BURNS. INHAL: EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT & CNS EFTS INCL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: DIZZ, WEAK, FATG, NAUS, HDCH & POSS UNCON. INGEST: CAN CAUSE GI IRRIT, NAUS, VOMIT & DIARR. CHRONIC: OVEREXP TO THIS MATL (OR ITS COMPONENTS) HAS APPARENTLY BEEN FOUND TO CAUSE LIVER ABNORMA LITIES IN LABORATORY ANIMALS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMD CLTHG. WASH EXPOS AREA W/SOAP & WATER. LAUNDER CONTAMD CLTHG BEFORE REUSE. IF SYMPS PERSIST, SEEK MED ATTN. EYES: IF SYMPS DEVELOP, MOVE PERSON AWAY FROM EXPOS & INTO FRESH AIR. F LUSH EYES FOR AT LEAST 15 MIN WHILE HOLDING LIDS APART. INGEST: IMMED DRINK 2 GLASSES OF WATER & INDUCE VOMIT BY EITHER GIVING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF THROAT. NEVER GIVE (ING 3) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:62.0F,16.7C Lower Limits:2% Upper Limits:12% Extinguishing Media:ALCOHOL FOAM OR CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLO. ALL 5 GAL PAILS & LARGER METAL CNTNRS INCL (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL:ELIM ALL SOURCES OF IGNIT SUCH AS FLARES, FLAMES (INCL PILOT LIGHTS) & ELEC SPKS. ABSORB LIQ ON VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC (ING 5) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR SOLID), ALL HAZ PRECS GIVEN IN MSDS MUST BE OBSERVED. Other Precautions:WARNING! SUDDEN RELS OF HOT ORG CHEM VAPS/MISTS FROM PROCESS EQUIP OPERATING AT ELEVATED TEMP & PRESS OR SUDDEN INGRESS OF AIR INTO VACUUM EQUIP, MAY RSLT IN IGNIT W/OUT PRESENCE OF OBVIOUS IGNIT SOUR CES. PUBLISHED "AUTOIGNIT" OR (ING 9) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD OR ANY COMPONENT IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RESPS (NE G PRESS TYPE) UNDER SPECIFIED (ING 12) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR IMPERVIOUS CLOTHING AND BOOTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: TANK CARS & TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATL IS TRANSFERRED. VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND OR MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMKNG, ELEC MOTORS, STATIC DISCHARGE OR OTHER IGNIT SOURCES AT LOCATIONS DISTANT FROM MATL HNDLG POINT. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:>175F,>79C Vapor Pres:33 @ 68F Vapor Density:2 Spec Gravity:0.809-0.814 Evaporation Rate & Reference:2 (N-BUTYL ACETATE=1) Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS, NITRIC ACID, SULFURIC ACID, ALDEHYDES, HALOGENS. Stability Condition to Avoid:DO NOT USE WITH ALUMINUM EQUIPMENT AT TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILLS: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.